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Which of the following options are not a...

Which of the following options are not accordance with the property mentioned against them?
(a) `F_(2)gtCl_(2)gtBr_(2)gtI_(2)` Oxodising power
(b) `MIgtMBrgtMClgtMF` Ionic character of metal halide
(c ) `F_(2)gtCl_(2)gtBr_(2)gtI_(2)` Bond dissociation enthalphy
(d) `HIltHBrltHClltHF` Hydrogen - halogen bond strength

Text Solution

AI Generated Solution

The correct Answer is:
To solve the question, we need to analyze each option provided and determine whether the order mentioned aligns with the properties described. Let's break it down step by step: ### Step 1: Analyzing Option (a) **Given Order:** \( F_2 > Cl_2 > Br_2 > I_2 \) **Property:** Oxidizing power **Analysis:** - Oxidizing power increases with the ability of an element to gain electrons. - Fluorine (F) has the highest oxidizing power due to its small size and high electronegativity, followed by chlorine (Cl), bromine (Br), and iodine (I). - Thus, the order is correct. ### Step 2: Analyzing Option (b) **Given Order:** \( MI > MBr > MCl > MF \) **Property:** Ionic character of metal halides **Analysis:** - Ionic character is determined by the electronegativity difference between the metal (M) and the halogen. - Fluorine (F) has the highest electronegativity, leading to the highest ionic character in \( MF \), followed by \( MCl \), \( MBr \), and \( MI \). - Therefore, the order given in the question is incorrect. ### Step 3: Analyzing Option (c) **Given Order:** \( F_2 > Cl_2 > Br_2 > I_2 \) **Property:** Bond dissociation enthalpy **Analysis:** - The bond dissociation enthalpy is affected by the size of the atoms and the repulsion between electrons. - Fluorine (F) has a lower bond dissociation enthalpy than chlorine (Cl) due to significant electron-electron repulsions in the small 2p orbital. - The correct order should be \( Cl_2 > Br_2 > F_2 > I_2 \). - Thus, the order given is incorrect. ### Step 4: Analyzing Option (d) **Given Order:** \( HI < HBr < HCl < HF \) **Property:** Hydrogen-halogen bond strength **Analysis:** - The bond strength decreases as the size of the halogen increases. - HF has the strongest bond due to the small size of fluorine and high electronegativity, followed by HCl, HBr, and HI. - Therefore, the order given is correct. ### Conclusion The options that are not in accordance with the properties mentioned are **(b) and (c)**. ### Final Answer: (b) and (c) are not in accordance with the properties mentioned. ---

To solve the question, we need to analyze each option provided and determine whether the order mentioned aligns with the properties described. Let's break it down step by step: ### Step 1: Analyzing Option (a) **Given Order:** \( F_2 > Cl_2 > Br_2 > I_2 \) **Property:** Oxidizing power **Analysis:** - Oxidizing power increases with the ability of an element to gain electrons. ...
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