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Which of the following statements are co...

Which of the following statements are correct ?
(a) All the three N___O bond lengths in `HNO_(3)` are equal.
(b) All P___Cl bond lengths in `PCl_(5)` molecule in gaseous state are equal
(c ) `P_(4)` molecule in white phosphrus have angular strain therefore white phosphorus is very reactive
(d) `PCl_(5)` is ionic in solid state in which cation is tetrahedral and anion is octahedral . And anion is octahedral.

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The correct Answer is:
To determine which statements are correct regarding the given compounds, let's analyze each statement step by step. ### Step 1: Analyze Statement (a) **Statement (a):** All the three N___O bond lengths in HNO₃ are equal. **Analysis:** - The structure of HNO₃ (Nitric acid) can be represented as: ``` O || H - N - O⁻ | O ``` - In this structure, there is one N=O double bond and two N-O single bonds. - Double bonds are shorter than single bonds, so the bond lengths cannot be equal. **Conclusion:** Statement (a) is **incorrect**. ### Step 2: Analyze Statement (b) **Statement (b):** All P___Cl bond lengths in PCl₅ molecule in gaseous state are equal. **Analysis:** - PCl₅ has a triangular bipyramidal structure with: - 3 equatorial P-Cl bonds - 2 axial P-Cl bonds - The equatorial bonds are shorter than the axial bonds due to the geometry of the molecule. **Conclusion:** Statement (b) is **incorrect**. ### Step 3: Analyze Statement (c) **Statement (c):** P₄ molecule in white phosphorus has angular strain; therefore, white phosphorus is very reactive. **Analysis:** - The P₄ molecule has a tetrahedral structure, which creates angular strain due to the bond angles being less than the ideal tetrahedral angle (109.5°). - This strain makes the molecule unstable and highly reactive. **Conclusion:** Statement (c) is **correct**. ### Step 4: Analyze Statement (d) **Statement (d):** PCl₅ is ionic in solid state in which cation is tetrahedral and anion is octahedral. **Analysis:** - In the solid state, PCl₅ dissociates into PCl₄⁺ (tetrahedral) and PCl₆⁻ (octahedral). - The tetrahedral cation and octahedral anion confirm the ionic nature of PCl₅ in solid state. **Conclusion:** Statement (d) is **correct**. ### Final Summary - **Correct Statements:** (c) and (d) - **Incorrect Statements:** (a) and (b)

To determine which statements are correct regarding the given compounds, let's analyze each statement step by step. ### Step 1: Analyze Statement (a) **Statement (a):** All the three N___O bond lengths in HNO₃ are equal. **Analysis:** - The structure of HNO₃ (Nitric acid) can be represented as: ``` ...
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