Home
Class 12
CHEMISTRY
Assertion(A): N,N-diethylbenzene sulphon...

Assertion(A): N,N-diethylbenzene sulphonamide is insoluble in alkali.
Reason(R ): Sulphonyl group attached to nitrogen atoms is strong electron withdrawing group.

A

Both assertion and reason are worng

B

Both assertion and reason are correct statement but reason is not correct explaination of assertion.

C

Assertion is correct statements and reason is correct explanation of assertion.

D

Both asseration and reason are correct statements and reason is correct explanation of assertion .

Text Solution

AI Generated Solution

To solve the question regarding the assertion and reason about N,N-diethylbenzene sulphonamide, we will analyze both statements step by step. ### Step 1: Analyze the Assertion **Assertion (A)**: N,N-diethylbenzene sulphonamide is insoluble in alkali. - **Explanation**: N,N-diethylbenzene sulphonamide contains a nitrogen atom bonded to two ethyl groups and a sulphonyl group. The nitrogen atom does not have any reactive acidic hydrogen. In general, for a compound to be soluble in alkali, it must have acidic protons that can react with the alkali to form soluble ions. Since this compound lacks such acidic hydrogen, it remains insoluble in alkali. ### Step 2: Analyze the Reason ...
Promotional Banner

Topper's Solved these Questions

  • AMINES

    NCERT EXEMPLAR ENGLISH|Exercise LONG ANSWER|3 Videos
  • AMINES

    NCERT EXEMPLAR ENGLISH|Exercise LONG ANSWER|3 Videos
  • ALDEHYDE, KETONES AND CARBOXYLIC ACIDS

    NCERT EXEMPLAR ENGLISH|Exercise Long Answer Type Questions|4 Videos
  • BIOMOLECULES

    NCERT EXEMPLAR ENGLISH|Exercise Long Answer Type Questions|5 Videos

Similar Questions

Explore conceptually related problems

Assertion (A): N-ethylbenzene sulphonamide is solube in alkali. Reason (R ): Hydrogen attached to nitrogen In sulphonamide is strongly acidic.

Assertion : N-Ethylbenzenessulphonamide is soluble in alkali . Reason : Hydrogen attached to nitrogen in sulphonamide is strongly acidic in nature .

Assertion(A) : Aniline hydrogen sulphate on heating froms a mixture of o- and p-amineo- sulphonic acid . Reason (R ) : The suphonic acid is electron withdrawing group.

Assertion (A) Sulpha drug contain sulphonamide group. Reason (R) Salvarsan is a sulpha drug.

Assertion: p-N, N- dimethylaminobenzaldehy under-goes benzoin condensation Reason : The aldehydic (-CHO) group is meta directing.

Assertion : N, N-Diethyl ethanamine is more basic the N, N-Dimethyl methanamine. Reason : +I effect of ethyl group is more then methyl

Assertion : Sulpha durgs contain sulphonamide group. Reason : Salvarsan is a sulpha drug.

Assertion (A) Presence of a nitro group at ortho or para position increases the reactivity of haloarenas towards nucleophilic substitution. Reason (R ) Nitro group, being an electron withdrawing group decreases the electron density over the benzene ring.

Assertion : p-nitroaniline is stronger base than p-toluidine . Reason: The electron withdrawing NO_(2) group in the p-nitroaniline makes it a stronger base .

Assertion (A) Nitration of chlorobenzene leads to the formation of m-nitrochlorobenzene. Reason (R) -NO_(2) group is a m-directing group.

NCERT EXEMPLAR ENGLISH-AMINES-SATQ
  1. Complete the following reaction

    Text Solution

    |

  2. Why is aniline soluble in aqueous HCl?

    Text Solution

    |

  3. Suggest a route by which of the following conversion can be accomplish...

    Text Solution

    |

  4. Identfy A and B in the following reactions.

    Text Solution

    |

  5. How will you carry out the follwing conversion? (i) Toluene -p-tolui...

    Text Solution

    |

  6. Write following conversions (i) Nitrobenzene-Acetanilide (ii) Acet...

    Text Solution

    |

  7. A solution contains 1g mol. Each of p-toluene diazonium chloride and p...

    Text Solution

    |

  8. How will you bring out the following conversion?

    Text Solution

    |

  9. How will you carry out the following conversion?

    Text Solution

    |

  10. How will you carry out the following conversion?

    Text Solution

    |

  11. How will you carry out the following conversion?

    Text Solution

    |

  12. Match the reactions given in Column I with the statements given in Col...

    Text Solution

    |

  13. Match the reactions given in Column I with the statements given in Col...

    Text Solution

    |

  14. Assertion(A) Acylation of amines gives a monsubstituted product where...

    Text Solution

    |

  15. Assertion (A): Hofmann's bromamide reaction is given by primary amines...

    Text Solution

    |

  16. Assertion (A): N-ethylbenzene sulphonamide is solube in alkali. Reas...

    Text Solution

    |

  17. Assertion(A): N,N-diethylbenzene sulphonamide is insoluble in alkali. ...

    Text Solution

    |

  18. Assertion(A): Only a small amount of HCl is required in the reduction ...

    Text Solution

    |

  19. Assertion(A): Aromatic 1^(@ amines can be prepared by Gabriel phtalmi...

    Text Solution

    |

  20. Assertion(A): Acetanilide is less basic aniline. Reson(R ): Acetylat...

    Text Solution

    |