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The rms speed of oxygen molecules in a g...

The rms speed of oxygen molecules in a gas in a gas is v. If the temperature is doubled and the oxygen molecules dissociate into oxygen atoms, the rms speed will become

A

(a)`v`

B

(b)`vsqrt(2)`

C

(c)`2v`

D

(d)`4v`

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The correct Answer is:
To solve the problem, we need to determine how the root mean square (rms) speed of oxygen changes when the temperature is doubled and the oxygen molecules dissociate into atoms. ### Step-by-Step Solution: 1. **Understand the formula for rms speed**: The rms speed (\(v_{rms}\)) of a gas is given by the formula: \[ v_{rms} = \sqrt{\frac{3kT}{m}} \] where \(k\) is the Boltzmann constant, \(T\) is the temperature, and \(m\) is the mass of a molecule. 2. **Identify the initial conditions**: We are given that the initial rms speed of oxygen molecules is \(v\). Therefore, we can write: \[ v = \sqrt{\frac{3kT}{m}} \] 3. **Determine the new temperature**: If the temperature is doubled, the new temperature \(T'\) becomes: \[ T' = 2T \] 4. **Consider the dissociation of molecules**: Oxygen molecules (O\(_2\)) dissociate into oxygen atoms (O). The molar mass of O\(_2\) is 32 amu, and for O, it is 16 amu. Thus, the mass of one oxygen atom \(m'\) is: \[ m' = \frac{m}{2} \] 5. **Substitute the new values into the rms speed formula**: The new rms speed (\(v'_{rms}\)) can be calculated using the new temperature and the new mass: \[ v'_{rms} = \sqrt{\frac{3kT'}{m'}} = \sqrt{\frac{3k(2T)}{m/2}} \] 6. **Simplify the expression**: Simplifying the above expression gives: \[ v'_{rms} = \sqrt{\frac{3k(2T) \cdot 2}{m}} = \sqrt{\frac{6kT}{m}} = \sqrt{2} \cdot \sqrt{\frac{3kT}{m}} = \sqrt{2} \cdot v \] 7. **Final result**: Therefore, the new rms speed after doubling the temperature and dissociating the molecules is: \[ v'_{rms} = 2v \] ### Conclusion: The rms speed will become \(2v\).
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