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In which fo the following has the oxidat...

In which fo the following has the oxidation number of oxygen been arragned in increasing order ?

A

`OF_(2) lt KO_(2) lt BaO_(2) lt O_(3)`

B

`BaO_(2) lt KO_(2) lt O_(3) lt OF_(2)`

C

`BaO_(2) lt KO_(2) lt OF_(2) lt KO_(2)`

D

` KO_(2) lt OF_(2) lt O_(3) lt BaO_(2)`

Text Solution

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The correct Answer is:
To determine the increasing order of oxidation numbers of oxygen in the given compounds, we will calculate the oxidation state of oxygen in each compound step by step. ### Step 1: Calculate the oxidation state of oxygen in OF2 - Let the oxidation state of oxygen be \( x \). - The oxidation state of fluorine (F) is \(-1\). - The compound OF2 has 2 fluorine atoms, so the equation becomes: \[ x + 2(-1) = 0 \] - Simplifying this gives: \[ x - 2 = 0 \implies x = +2 \] ### Step 2: Calculate the oxidation state of oxygen in KO2 - In KO2, potassium (K) has an oxidation state of \( +1 \). - Let the oxidation state of oxygen be \( x \). - The compound KO2 contains two oxygen atoms, so the equation becomes: \[ +1 + 2x = 0 \] - Simplifying this gives: \[ 2x = -1 \implies x = -\frac{1}{2} \] ### Step 3: Calculate the oxidation state of oxygen in BaO2 - In BaO2, barium (Ba) has an oxidation state of \( +2 \). - Let the oxidation state of oxygen be \( x \). - The compound BaO2 contains two oxygen atoms, so the equation becomes: \[ +2 + 2x = 0 \] - Simplifying this gives: \[ 2x = -2 \implies x = -1 \] ### Step 4: Calculate the oxidation state of oxygen in O3 - In O3 (ozone), all oxygen atoms are the same, and the oxidation state is: \[ x + x + x = 0 \implies 3x = 0 \implies x = 0 \] ### Step 5: Arrange the oxidation states in increasing order Now we have the oxidation states of oxygen in each compound: - OF2: \( +2 \) - KO2: \( -\frac{1}{2} \) - BaO2: \( -1 \) - O3: \( 0 \) Arranging these in increasing order: 1. BaO2: \( -1 \) 2. KO2: \( -\frac{1}{2} \) 3. O3: \( 0 \) 4. OF2: \( +2 \) Thus, the increasing order of oxidation numbers of oxygen is: **BaO2 < KO2 < O3 < OF2** ### Final Answer The correct option is **B**.
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