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Oxidation number of P in Ba(H(2)PO(2))(2...

Oxidation number of `P` in `Ba(H_(2)PO_(2))_(2)` is

A

`-1`

B

`+1`

C

`+2`

D

`+3`

Text Solution

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The correct Answer is:
To find the oxidation number of phosphorus (P) in the compound \( Ba(H_2PO_2)_2 \), we can follow these steps: ### Step-by-Step Solution 1. **Identify the oxidation states of known elements**: - Barium (Ba) is an alkaline earth metal and typically has an oxidation state of +2. - Hydrogen (H) generally has an oxidation state of +1. - Oxygen (O) usually has an oxidation state of -2. 2. **Write the formula for the compound**: - The compound is \( Ba(H_2PO_2)_2 \). This means there are two \( H_2PO_2 \) groups in the formula. 3. **Calculate the total contribution from barium**: - Since there are two barium ions, the total contribution from barium is: \[ 2 \times (+2) = +4 \] 4. **Calculate the contribution from hydrogen**: - Each \( H_2PO_2 \) group contains 2 hydrogen atoms, and since there are 2 groups, the total number of hydrogen atoms is: \[ 2 \times 2 = 4 \] - The total contribution from hydrogen is: \[ 4 \times (+1) = +4 \] 5. **Calculate the contribution from oxygen**: - Each \( H_2PO_2 \) group contains 2 oxygen atoms, and since there are 2 groups, the total number of oxygen atoms is: \[ 2 \times 2 = 4 \] - The total contribution from oxygen is: \[ 4 \times (-2) = -8 \] 6. **Set up the equation for the oxidation state of phosphorus (P)**: - Let the oxidation state of phosphorus be \( x \). - The total charge of the compound must equal zero. Therefore, we can set up the equation: \[ (+4) + (+4) + (x \text{ from P}) + (-8) = 0 \] 7. **Simplify the equation**: - Combine the known contributions: \[ 4 + 4 - 8 + x = 0 \] \[ 0 + x = 0 \] 8. **Solve for \( x \)**: - This simplifies to: \[ x = +1 \] ### Conclusion The oxidation number of phosphorus (P) in \( Ba(H_2PO_2)_2 \) is **+1**.
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