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1 mole of Ba(OH)(2) will exactly neutral...

1 mole of `Ba(OH)_(2)` will exactly neutralize :

A

0.5 mole HCL

B

1 mole of `H_(2)SO_(4)`

C

1 mole of `H_(3)PO_(3)`

D

2 mole of `H_(3)PO_(2)`

Text Solution

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The correct Answer is:
To solve the question of how many moles of various acids can be exactly neutralized by 1 mole of barium hydroxide (Ba(OH)₂), we need to follow these steps: ### Step-by-Step Solution 1. **Identify the Reaction**: Barium hydroxide is a strong base that dissociates in water to produce Ba²⁺ and OH⁻ ions. The dissociation can be represented as: \[ \text{Ba(OH)}_2 \rightarrow \text{Ba}^{2+} + 2 \text{OH}^- \] 2. **Determine the Number of Equivalents of Ba(OH)₂**: The number of equivalents of a substance is calculated as: \[ \text{Number of equivalents} = \text{Number of moles} \times n \text{ factor} \] For barium hydroxide, since it produces 2 hydroxide ions (OH⁻), the n factor is 2. Therefore, for 1 mole of Ba(OH)₂: \[ \text{Number of equivalents of Ba(OH)}_2 = 1 \text{ mole} \times 2 = 2 \text{ equivalents} \] 3. **Analyze Each Acid Option**: We will calculate the number of equivalents for each acid option provided. - **Option A: 0.5 moles of HCl**: HCl dissociates to produce 1 H⁺ ion: \[ \text{Number of equivalents of HCl} = 0.5 \text{ moles} \times 1 = 0.5 \text{ equivalents} \] This is not enough to neutralize 2 equivalents of Ba(OH)₂. - **Option B: 1 mole of H₂SO₄**: H₂SO₄ dissociates to produce 2 H⁺ ions: \[ \text{Number of equivalents of H}_2\text{SO}_4 = 1 \text{ mole} \times 2 = 2 \text{ equivalents} \] This exactly neutralizes 2 equivalents of Ba(OH)₂. - **Option C: 1 mole of H₃PO₃**: H₃PO₃ can release 2 H⁺ ions: \[ \text{Number of equivalents of H}_3\text{PO}_3 = 1 \text{ mole} \times 2 = 2 \text{ equivalents} \] This also exactly neutralizes 2 equivalents of Ba(OH)₂. - **Option D: 2 moles of H₃PO₂**: H₃PO₂ can release only 1 H⁺ ion: \[ \text{Number of equivalents of H}_3\text{PO}_2 = 2 \text{ moles} \times 1 = 2 \text{ equivalents} \] This also exactly neutralizes 2 equivalents of Ba(OH)₂. 4. **Conclusion**: The acids that can exactly neutralize 1 mole of Ba(OH)₂ are: - 1 mole of H₂SO₄ - 1 mole of H₃PO₃ - 2 moles of H₃PO₂ ### Final Answer: 1 mole of Ba(OH)₂ will exactly neutralize: - 1 mole of H₂SO₄ - 1 mole of H₃PO₃ - 2 moles of H₃PO₂
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