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STATEMENT-1 : In the given reaction, NaO...

STATEMENT-1 : In the given reaction, `NaOH+H_(3)PO_(4)rarr NaH_(2)PO_(4)+H_(2)O` equivalent mass of `H_(3)PO_(4)` is `M//3`
STATEMENT-2 : `H_(3)PO_(4)` is tribasic acid.

A

If both the statement are TRUE and STATEMENT -2 is the correct explanation of STATEMENT-1

B

If both the statement are TRUE but STATEMENT-2 is NOT the correct explanation of STATEMENT-1

C

If STATEMENT- is 1 TRUE and STATEMENT-2 is FALSE

D

If STATEMENT-1 is FALSE and STATEMENT-2 is TRUE

Text Solution

AI Generated Solution

The correct Answer is:
To solve the problem, we will analyze both statements provided and determine their validity step-by-step. ### Step 1: Understanding the Reaction The reaction given is: \[ \text{NaOH} + \text{H}_3\text{PO}_4 \rightarrow \text{NaH}_2\text{PO}_4 + \text{H}_2\text{O} \] ### Step 2: Identifying the Acid and Its Properties In this reaction, \( \text{H}_3\text{PO}_4 \) (phosphoric acid) is acting as an acid. It can donate protons (H⁺ ions) to the base (NaOH). ### Step 3: Determining the Equivalent Mass The equivalent mass of an acid is calculated using the formula: \[ \text{Equivalent mass} = \frac{\text{Molecular mass}}{n} \] where \( n \) is the number of replaceable H⁺ ions (or OH⁻ ions for bases). ### Step 4: Finding the n Factor for \( \text{H}_3\text{PO}_4 \) - \( \text{H}_3\text{PO}_4 \) is a tribasic acid, meaning it can donate up to 3 H⁺ ions. - In the reaction, \( \text{H}_3\text{PO}_4 \) donates 1 H⁺ ion to form \( \text{NaH}_2\text{PO}_4 \). Therefore, in this specific reaction, the n factor is 1. ### Step 5: Calculating the Equivalent Mass of \( \text{H}_3\text{PO}_4 \) Given that the molecular mass of \( \text{H}_3\text{PO}_4 \) is \( M \): \[ \text{Equivalent mass} = \frac{M}{n} = \frac{M}{1} = M \] ### Step 6: Evaluating Statement 1 Statement 1 claims that the equivalent mass of \( \text{H}_3\text{PO}_4 \) is \( \frac{M}{3} \). Since we calculated it to be \( M \), this statement is **incorrect**. ### Step 7: Evaluating Statement 2 Statement 2 states that \( \text{H}_3\text{PO}_4 \) is a tribasic acid. Since it can donate 3 H⁺ ions, this statement is **correct**. ### Conclusion - Statement 1 is false. - Statement 2 is true. Thus, the correct option is that Statement 1 is incorrect and Statement 2 is correct.
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