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STATEMENT-1 : I(2)rarrIO(3)^(-)+I^(-), i...

STATEMENT-1 : `I_(2)rarrIO_(3)^(-)+I^(-)`, is example of a disproportionation reaction.
STATEMENT-2 : Oxidation number of I can vary from `-1` to `+7`.

A

If both the statement are TRUE and STATEMENT -2 is the correct explanation of STATEMENT-1

B

If both the statement are TRUE but STATEMENT-2 is NOT the correct explanation of STATEMENT-1

C

If STATEMENT- is 1 TRUE and STATEMENT-2 is FALSE

D

If STATEMENT-1 is FALSE and STATEMENT-2 is TRUE

Text Solution

AI Generated Solution

The correct Answer is:
To solve the question, we need to analyze both statements regarding the reaction involving iodine. ### Step 1: Analyze Statement 1 The reaction given is: \[ I_2 \rightarrow IO_3^{-} + I^{-} \] This reaction involves iodine (I) in its elemental form (I2) transforming into iodate (IO3-) and iodide (I-). ### Step 2: Determine the Oxidation States - In \( I_2 \), the oxidation state of iodine is 0 (since it is in its elemental form). - In \( IO_3^{-} \): - Let the oxidation state of iodine be \( x \). - The oxidation state of oxygen is -2. - Therefore, for three oxygen atoms, the total contribution is \( -6 \). - The overall charge of the ion is -1, leading to the equation: \[ x - 6 = -1 \] \[ x = +5 \] - In \( I^{-} \), the oxidation state of iodine is -1. ### Step 3: Identify Oxidation and Reduction - The oxidation state of iodine changes from 0 in \( I_2 \) to +5 in \( IO_3^{-} \) (oxidation). - The oxidation state changes from 0 in \( I_2 \) to -1 in \( I^{-} \) (reduction). Since iodine is both oxidized (to +5) and reduced (to -1) in this reaction, it is classified as a disproportionation reaction. ### Conclusion for Statement 1 Thus, Statement 1 is correct: the reaction is indeed an example of a disproportionation reaction. ### Step 4: Analyze Statement 2 Statement 2 claims that the oxidation number of iodine can vary from -1 to +7. - Iodine can have an oxidation state of -1 when it gains an electron (as in \( I^{-} \)). - It can also have oxidation states up to +7 in compounds such as \( IO_4^{-} \) (where it loses up to 7 electrons). ### Conclusion for Statement 2 Thus, Statement 2 is also correct: the oxidation number of iodine can vary from -1 to +7. ### Final Evaluation Both statements are true, but Statement 2 does not explain Statement 1 directly. Therefore, the correct option is that both statements are true, but Statement 2 is not the correct explanation of Statement 1. ### Summary of Answers - **Statement 1**: True (disproportionation reaction) - **Statement 2**: True (oxidation states of iodine)
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