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Each question contains STATEMENT-1 (Asse...

Each question contains STATEMENT-1 (Assertion) and STATEMENT-2( Reason).
Examine the statements carefully and mark the correct answer according to the instruction given below:
STATEMENT-1: Equilibrium constant for the reverse reaction is the inverse of the equilibrium constant for the reaction in the forward direction.
STATEMENT-2: Equilibrium constant depends upon the way in which the reaction is written.

A

(a) If both the statements are TRUE and STATEMENT-2 is the correct explanation of STATEMENT-1

B

(b) both the statement are TRUE but STATEMENT-2 is NOT the correct explanation of STATEMENT-1

C

(c) If STATEMENT-1 is TRUE and STATEMENT-2 is FALSE

D

(d) If STATEMENT-1 is FALSE and STATEMENT-2 is TRUE

Text Solution

AI Generated Solution

The correct Answer is:
To solve the question, we need to analyze both statements provided: **STATEMENT-1**: Equilibrium constant for the reverse reaction is the inverse of the equilibrium constant for the reaction in the forward direction. **STATEMENT-2**: Equilibrium constant depends upon the way in which the reaction is written. ### Step-by-Step Solution: 1. **Understanding Equilibrium Constant**: - The equilibrium constant (K) for a reaction at equilibrium is defined as the ratio of the concentrations of products to reactants, each raised to the power of their respective stoichiometric coefficients. 2. **Writing the Forward Reaction**: - Consider a general reaction: \[ aA + bB \rightleftharpoons cC + dD \] - The equilibrium constant for this forward reaction (K) can be expressed as: \[ K = \frac{[C]^c [D]^d}{[A]^a [B]^b} \] 3. **Writing the Reverse Reaction**: - The reverse reaction would be: \[ cC + dD \rightleftharpoons aA + bB \] - The equilibrium constant for this reverse reaction (K') can be expressed as: \[ K' = \frac{[A]^a [B]^b}{[C]^c [D]^d} \] 4. **Relating K and K'**: - If we compare K and K', we can see that: \[ K' = \frac{1}{K} \] - This shows that the equilibrium constant for the reverse reaction is indeed the inverse of the equilibrium constant for the forward reaction. 5. **Analyzing STATEMENT-1**: - Since we have established that the equilibrium constant for the reverse reaction is the inverse of that for the forward reaction, **STATEMENT-1 is true**. 6. **Analyzing STATEMENT-2**: - The equilibrium constant does depend on how the reaction is written. For instance, if we reverse a reaction or multiply the coefficients by a factor, the equilibrium constant will change accordingly. - Thus, **STATEMENT-2 is also true**. 7. **Conclusion**: - Both statements are true, and STATEMENT-2 provides the correct explanation for STATEMENT-1. Therefore, the correct answer is that both statements are true, and the reason is the correct explanation of the assertion. ### Final Answer: Both statements are true, and statement 2 is the correct explanation of statement 1. ---
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