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when an aqueous solution of H2SO4 is ele...

when an aqueous solution of `H_2SO_4` is electrolysed the product at anodes is :

A

`H^-`

B

`OH^-`

C

`SO_4^(2-)`

D

`O_2`

Text Solution

AI Generated Solution

The correct Answer is:
To determine the product at the anode when an aqueous solution of \( H_2SO_4 \) (sulfuric acid) is electrolyzed, we can follow these steps: ### Step 1: Understand the Electrolysis Process Electrolysis involves the breakdown of a compound into its components using electricity. In the case of \( H_2SO_4 \), it dissociates into ions in an aqueous solution. ### Step 2: Identify the Ions Present In an aqueous solution of sulfuric acid, the dissociation can be represented as: \[ H_2SO_4 \rightarrow 2H^+ + SO_4^{2-} \] This means we have \( H^+ \) ions, \( SO_4^{2-} \) ions, and water molecules present in the solution. ### Step 3: Determine the Reaction at the Cathode At the cathode, reduction occurs. The \( H^+ \) ions gain electrons to form hydrogen gas: \[ 2H^+ + 2e^- \rightarrow H_2 \] This indicates that hydrogen gas is produced at the cathode. ### Step 4: Determine the Reaction at the Anode At the anode, oxidation occurs. The hydroxide ions (\( OH^- \)) can be formed from water, and the water molecules can also participate in the reaction. The overall reaction at the anode can be represented as: \[ 2H_2O \rightarrow O_2 + 4H^+ + 4e^- \] This indicates that oxygen gas is produced at the anode. ### Step 5: Conclusion Based on the reactions occurring at both electrodes, the product at the anode during the electrolysis of an aqueous solution of \( H_2SO_4 \) is oxygen gas (\( O_2 \)). ### Final Answer The product at the anode is \( O_2 \). ---
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