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Select the correct cell reaction of the ...

Select the correct cell reaction of the cell `Ag(s)|Ag^+(aq)"||"cu^(2+)(aq)"|"cu(s)`:

A

`2Ag(s)+cu(s)tocu^(+2)(aq)+2Ag^+(aq)`

B

`cu(s)+2Ag^+(aq)tocu^(2+)(aq)+2Ag(s)`

C

`2Ag(s)+cu^(2+)(aq)tocu(s)(aq)+2Ag^+(aq)`

D

`cu^(2+)(aq)+2Ag^+(aq)to2Ag(s)+cu(s)`

Text Solution

AI Generated Solution

The correct Answer is:
To determine the correct cell reaction for the electrochemical cell represented as `Ag(s)|Ag^+(aq)"||"Cu^(2+)(aq)"|"Cu(s)`, we need to analyze the oxidation and reduction processes occurring in the cell. ### Step-by-Step Solution: 1. **Identify the Anode and Cathode:** - In the given cell representation, the left side (Ag|Ag⁺) represents the anode where oxidation occurs. - The right side (Cu²⁺|Cu) represents the cathode where reduction occurs. 2. **Write the Oxidation Half-Reaction:** - At the anode, silver (Ag) is oxidized to silver ions (Ag⁺). The half-reaction can be written as: \[ \text{Ag(s)} \rightarrow \text{Ag}^+(aq) + e^- \] 3. **Write the Reduction Half-Reaction:** - At the cathode, copper ions (Cu²⁺) are reduced to solid copper (Cu). The half-reaction can be written as: \[ \text{Cu}^{2+}(aq) + 2e^- \rightarrow \text{Cu(s)} \] 4. **Balance the Electrons:** - To combine the half-reactions, we need to ensure that the number of electrons lost in oxidation equals the number of electrons gained in reduction. The oxidation half-reaction produces 1 electron, while the reduction half-reaction consumes 2 electrons. Therefore, we multiply the oxidation half-reaction by 2: \[ 2\text{Ag(s)} \rightarrow 2\text{Ag}^+(aq) + 2e^- \] 5. **Combine the Half-Reactions:** - Now, we can add the balanced half-reactions: \[ 2\text{Ag(s)} + \text{Cu}^{2+}(aq) \rightarrow 2\text{Ag}^+(aq) + \text{Cu(s)} \] 6. **Final Cell Reaction:** - The overall cell reaction is: \[ 2\text{Ag(s)} + \text{Cu}^{2+}(aq) \rightarrow 2\text{Ag}^+(aq) + \text{Cu(s)} \] ### Conclusion: The correct cell reaction for the electrochemical cell `Ag(s)|Ag^+(aq)"||"Cu^(2+)(aq)"|"Cu(s)` is: \[ 2\text{Ag(s)} + \text{Cu}^{2+}(aq) \rightarrow 2\text{Ag}^+(aq) + \text{Cu(s)} \]
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