To distinguish between glucose and fructose, we can follow these steps:
### Step-by-Step Solution:
1. **Understanding the Compounds**:
- Glucose is an aldose (a sugar with an aldehyde group).
- Fructose is a ketose (a sugar with a ketone group).
2. **Identifying the Tests**:
- We have four tests to consider: Barfoed's test, Fehling's solution, Benedict's test, and Selivanoff's test.
3. **Analyzing Barfoed's Test**:
- Barfoed's test is used to detect monosaccharides. Both glucose and fructose will give a positive result in this test, as they are both monosaccharides. Therefore, this test cannot distinguish between them.
4. **Analyzing Fehling's Solution**:
- Fehling's solution is used for reducing sugars. Both glucose and fructose will also give a positive result in this test because fructose can be converted to glucose in an alkaline medium. Thus, this test is also not suitable for distinguishing between glucose and fructose.
5. **Analyzing Benedict's Test**:
- Benedict's test is similar to Fehling's solution and is also used for reducing sugars. Since both glucose and fructose are reducing sugars, this test will not differentiate between them either.
6. **Analyzing Selivanoff's Test**:
- Selivanoff's test specifically distinguishes between aldoses and ketoses. In this test, glucose (aldose) reacts differently compared to fructose (ketose). Therefore, this test can effectively distinguish between glucose and fructose.
7. **Conclusion**:
- The most suitable test to distinguish between glucose and fructose is the Selivanoff's test.
### Final Answer:
Glucose and fructose can be distinguished by **Selivanoff's test**.
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