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Complete the reactions : (i) CH(2)=CH(...

Complete the reactions :
(i) `CH_(2)=CH_(2)+PdCl_(2) +H_(2)O overset(CuCl_2) underset(H^(+))rarr`
(ii) `CH_3- CH = CH_2+PdCl_2+H_2Ounderset(H^(+))overset(CuCl_2)rarr`

Answer

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+H_(2)NCH_(2)CH_(3) overset(H^(+))rarr

Write the structures of the products (i) C_(6)H_(6) + C_(2)H_(5C)OCl underset(CS_(2))overset(AlCl_(3))rarr (ii) CH_(3)underset(H_(3)O^(+))overset(CrO_(2)Cl_(2))rarr

Knowledge Check

  • CH_(3)-CH_(2)-CH=CH-CH_(3)+O_(3)underset("Zn")overset(H_(2)O)rarr

    A
    `CH_(3)CH_(2)CHO & CH_(3)CHO`, each one mole
    B
    Two moles of `CH_(3)CH_(2)CHO`
    C
    Two moles of `CH_(3)CHO`
    D
    `CH_(3)-CH_(2)-CH-CH=CH_(3)`

  • The reaction CH_(3)-CH_(2)-CH_(2)-CH_3 overset(HCl " Gas")underset(AlCl_3)rarr CH_(3) - underset(CH_(3))underset(|)(CH)-CH_(3) , is an example of

    A
    Isomerisation
    B
    Polymerisation
    C
    Cracking
    D
    Dehydrogenation

  • CH_(2)=CH_(2)+O_(3)underset(H_(2)O)overset(Zn)rarrXoverset("Reduction")rarrY.Y is

    A
    `CH_(4)`
    B
    `C_(2)H_(5)OH`
    C
    `CH_(3)OH`
    D
    `HCOH`

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    Write the structure of the major organic product in each of the following reactions: (i) CH_(3)CH_(2)CH_(2)Cl+NaIoverset("acetone")underset("heat")rarr (ii) (CH_(3))_(3)CBr+KOH overset("ethanol")underset("heat")rarr (iii) CH_(3)CH(Br)CH_(2)CH_(3)+NaOH overset("water")rarr (iv) CH_(3)CH_(2)Br+KCN overset("aq. ethanol")rarr (v) C_(6)H_(5)ONa+C_(2)H_(5)Clrarr (vi) CH_(3)CH_(2)CH=CH_(2)+HBr overset("peroxide")rarr (viii) CH_(3)CH=C(CH_(3))_(2)+HBr rarr

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    In the reaction :- H_2C = CH - CH = CH_2 underset(180^(@)C)overset(Br_2)toX 'X' will be

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