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Acetophenone when reacted with a base, C...

Acetophenone when reacted with a base, `C_(2)H_(5)O Na`, yields a stable compound which has the structure

A

B

C

D

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The correct Answer is:
A
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C_(2)H_(5)^(+) is more stable than CH,+. Substantiate ?

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A primary alkyl halide C_(4)H_(9) Br (A) reacted with alcoholic KOH to give compound B . B on reaction with HBr yields C which is an isomer of A . When A is reacted with sodium metal forms D , C_(6) H_(8) which is different from the compound formed when n-butylbromide is reacted with sodium . Give the structural formulae of A-D and write equations for all the reactions .

An organic compound ‘A’ has molecular formula C_(9)H_(13)NO and it can be resolve into enantiomers. Adoes not decolourise bromine water solution. A on refluxing with dilute H_(2)SO_(4) , yields another revolvable compound B(C_(9)H_(14)O_(3)) which give effervescence with NaHCO_(3) . B on treatment with NaBH_(4) yields C(C_(9)H_(16)O_(3)) on heating with concentrated H_(2)SO_(4) yields ester D (C_(6)H_(14)O_(2)) . Compound A on reduction with LiAlH_(4) followed by treatment of H_(2)SO_(4) yields following compound : The sweet smelling neutral compound D is

An organic compound ‘A’ has molecular formula C_(9)H_(13)NO and it can be resolve into enantiomers. Adoes not decolourise bromine water solution. A on refluxing with dilute H_(2)SO_(4) , yields another revolvable compound B(C_(9)H_(14)O_(3)) which give effervescence with NaHCO_(3) . B on treatment with NaBH_(4) yields C(C_(9)H_(16)O_(3)) on heating with concentrated H_(2)SO_(4) yields ester D (C_(6)H_(14)O_(2)) . Compound A on reduction with LiAlH_(4) followed by treatment of H_(2)SO_(4) yields following compound : Due to reduction of optically pure 'B'two isomeric product 'C' form. Isomeric product 'C' are :

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AAKASH SERIES-ALDEHYDES AND KETONES-Objective exercise -3 (Previous NEET/AIPMT Questions)
  1. (CH(3))(2)C=CHCOCH(3) can be oxidised to (CH(3))(2)C=CHCOOH by

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  2. Benzaldehyde reacts with ethanolic KCN to give

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  3. Acetophenone when reacted with a base, C(2)H(5)O Na, yields a stable c...

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  4. The reagents which can be used to distinguish acetophenone from benzop...

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  5. Among the given compounds, the most susceptible to nucleophilic attack...

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  6. , the compound describes a condensation polymer which can be obtained ...

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  7. In a set of reactions m-bromobenzoic acid gave a product D. overset...

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  8. Predict the products in the given reaction.

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  9. CH(3)CHO and C(6)H(5)CHO can be distinguished chemically by

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  10. Consider the following reaction underset(Pd-BaSO(4))overset(H(2))ra...

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  11. Consider the reaction : RCHO + NH(2)NH(2) rarr RCH = N-NH(2) What ...

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  12. Acetone is treated with excess of ethanol in the presence of hydrochlo...

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  13. Reaction by which benzaldehyde cannot be prepared

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  14. Which one is most reactive towards nucleophilic addition reaction ?

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  15. An organic compound 'X' having molecular formula C(5)H(10) yields phen...

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  16. Reaction of a carbonyl compound with one of the following reagents inv...

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  17. Reaction of a carbonyl compound with one of the following reagents inv...

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  18. Which of the following compounds would be hydrolysed most easily ?

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  19. The correct statement regarding a carbonly compound with a hydrogen at...

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  20. Which among the given molecules are exhibit tautomerism?

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