Home
Class 12
CHEMISTRY
C(6)H(6) + C(2)H(5)Cl overset(AlCl(3))ra...

`C_(6)H_(6) + C_(2)H_(5)Cl overset(AlCl_(3))rarr X underset((CH_(3)COO)_(2)Mn)overset("Oxygen")rarr Y overset(H_(2)Cr_(2)O_(7))rarr Z`
Discuss the sequence and name the compounds X, Y and Z

Text Solution

Verified by Experts

Compound X is ethylbenzene, `C_(6)H_(5)C_(2)H_(5)`. The reaction is called Friedel-Crafts ethylation. Y is acetophenone, `C_(6)H_(5)COCH_(3)`. Oxidation of ethyl benzene at 400K in the presence of manganese acetate catalyst gives acetophenone. Z is benzoic acid, `C_(6)H_(5)COOH`. Aromatic ketones give carboxylic acids in the presence of powerful oxidants.
Promotional Banner

Topper's Solved these Questions

  • ALDEHYDES AND KETONES

    AAKASH SERIES|Exercise Exercise-3.1.1|5 Videos
  • ALDEHYDES AND KETONES

    AAKASH SERIES|Exercise Exercise-3.1.2|24 Videos
  • ALDEHYDES AND KETONES

    AAKASH SERIES|Exercise Conversions (Name Reaction and reagents :)|24 Videos
  • ALCOHOLS, PHENOLS AND ETHERS

    AAKASH SERIES|Exercise ETHERS (OBJECTIVE EXERCISE-4)|50 Videos
  • ALKYL AND ARYL HALIDES

    AAKASH SERIES|Exercise OBJECTIVE EXERCISE - 4 (ASSERTION (A) & REASON (R) TYPE QUESTIONS)|19 Videos

Similar Questions

Explore conceptually related problems

C_6H_6+C_2H_5Cloverset(AlCl_3)rarrXoverset("Oxygen")rarrYoverset(H_2Cr_2O_7)rarr Z. Discuss and name the compounds X , Y and Z.

overset(Mg)rarr X overset(CO_(2))rarr Y overset(H_(2)O)rarr Z

+H_(2)NCH_(2)CH_(3) overset(H^(+))rarr

HCHO overset(CH_(3)MgBr)rarrA overset(H_(2)O)rarr B underset(H^(+))overset(K_(2)Cr_(2)O_(7))rarrC . What is the product 'C'?

CH_(3)- CH = CH_(2) + H_(2)O + PdCl_(2) overset(CuCl_(2))rarr X underset(-2H_(2)O)overset(HCl)rarr Y . What is 'Y' ?

C_(6)H_(6) +CO + HCl overset("Anhyd."AlCl_(3))rarr X + HCl Compound X is

(CH_(3))_(2)CO underset((HCl))overset(NaCN)rarr A underset(Delta)overset(H_(3)O^(+))rarr B . In the above sequence A and B are

C_(2)H_(5)Cl overset(KCN) rarr X overset(H_(2)//"Catalyst")rarr Y overset(CHCl_(3)) underset(alc, KOH) rarr Z What is 'Z' in the above sequence of reactions ?

C_(6)H_(5)NH_(2) underset(H_(2)O)overset(Br_(2))rarr A underset(0^(@)C)overset(NaNO_(2), HCl)rarr B overset(H_(3)PO_(2))rarr C . Identify the organic product 'C'. Write the reactions

C_(3)H_(8)O underset(K_(2)Cr_(2)O_(7)//H^(+))overset((O))rarr C_(3)H_(6)O overset(I_(2)//NaOH)rarr CHI_(3) In this sequence, the starting compound is

AAKASH SERIES-ALDEHYDES AND KETONES-Problem
  1. Arrange the following compounds in increasing order of their reactivit...

    Text Solution

    |

  2. Compound A, C5H(10)O, forms a phenyl hyrazone, given negative Tollen's...

    Text Solution

    |

  3. An organic compound (A) with molecular formula C(8)H(8)O forms an oran...

    Text Solution

    |

  4. An alkene , C6H(12) after ozonolysis yielded two products. One of thes...

    Text Solution

    |

  5. Two organic compounds (A) and (B) with molecular formula, C3H6O , reac...

    Text Solution

    |

  6. Although aldehydes are easily oxidisable, propanal can conveniently be...

    Text Solution

    |

  7. Aldehydes do not form stable hydrates, yet chloral hydrate is readily ...

    Text Solution

    |

  8. How is acetaldehyde distinguished from acetone?

    Text Solution

    |

  9. What are metaldehyde and paraldehyde?

    Text Solution

    |

  10. What products are obtained in a crossed Cannizzaro reaction, involving...

    Text Solution

    |

  11. An organic compound having molecular formula C5H(10) O exists in two c...

    Text Solution

    |

  12. Benzaldehyde is treated with acetaldehyde in presence of dilute alkali...

    Text Solution

    |

  13. How do you distingush between benzaldehyde and acetophenone?

    Text Solution

    |

  14. Given the structures of the compounds formed when the reaction takes p...

    Text Solution

    |

  15. C(6)H(6) + C(2)H(5)Cl overset(AlCl(3))rarr X underset((CH(3)COO)(2)Mn)...

    Text Solution

    |

  16. How do you prepare acetophenone from benzene?

    Text Solution

    |

  17. What is the rate determining step in Cannizzaro's reaction?

    Text Solution

    |

  18. Predict products in the following reactions and write their structures...

    Text Solution

    |

  19. Can (CH3)3 CCHO undergo Cannizzaro reaction ?

    Text Solution

    |

  20. C(6)H(6) + C(2)H(5)Cl overset(AlCl(3))rarr X underset((CH(3)COO)(2)Mn)...

    Text Solution

    |