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What is the orientation effect of aldehy...

What is the orientation effect of aldehydic and ketonic group when attached to aromatic ring towards electrophilic substitution reactions?

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Explain OH group attached to benzene ring activates it towards electrophilic substitution.

Among the following which is less reactive towards electrophilic substitution reactions

Why toluene is more reactive than benzene towards electrophilic substitution reactions?

Why toluene is more reactive than benzene towards electrophilic substitution reactions?

Discuss the effect of nitro group in chloro benzene towards nucleophilic substitution reaction.

Write a note on deactivating groups towards electrophilic substitution in benzene.

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The typical reaction of benzene and other aromatic compounds is electrophilic substitution. Presence of electron donating group activates the ring towards electrophilic substitution, while presence of electron withdrawing group deactivates the ring towards electrophilic substitution but at the same time activates the ring towards nucleophilic substitution. Some groups are predominantly meta directing and all of these are deactivating. Except halogen, most of the o- and p- directing groups are activating groups. (E.A.S = Electrophilic aromatic substation) Presence of nitro group in benzene ring:

The typical reaction of benzene and other aromatic compounds is electrophilic substitution. Presence of electron donating group activates the ring towards electrophilic substitution, while presence of electron withdrawing group deactivates the ring towards electrophilic substitution but at the same time activates the ring towards nucleophilic substitution. Some groups are predominantly meta directing and all of these are deactivating. Except halogen, most of the o- and p- directing groups are activating groups. (E.A.S = Electrophilic aromatic substation) The reaction of toluene with Cl_2 in presence of FeCl_3 gives predominantly:

AAKASH SERIES-ALDEHYDES AND KETONES-Exercise 3.2
  1. Ring structure of glucose is due to formation of hemiacetal and ring f...

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  2. Write on the following (a) Stephens reaction and (b) Tischenko reactio...

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  3. Write notes on (i) Rosenmund reduction and (ii) Wolff-Kishner's reduct...

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  4. Describe any four methods of preparation of acetophenone?

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  5. What is the orientation effect of aldehydic and ketonic group when att...

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  6. What is Tollens reagent ? Explain its reaction with Aldehydes.

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  7. Write all the possible aldol products of 6-ketoheptanal

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  8. Write the products of reactions of ammonia with formaldehyde, acetalde...

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  9. Oxidation of toluene with CrO(3) in presence of acetic anhydride is be...

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  10. Write the sequence of reactions to convert acetylene into acetophenone

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  11. (CH(3))(3)C CHO does not undergo Cannizzaro's reaction. Why?

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  12. Write the products of the reaction in presence of base between propana...

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  13. CH(3)- CH = CH(2) + H(2)O + PdCl(2) overset(CuCl(2))rarr X underset(-2...

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  14. CH(3)CHO underset(H(2)SO(4))overset(K(2)Cr(2)O(7))rarrA overset(NaOH)r...

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  15. CH(3)CHO overset("Chromic acid")rarr A overset(Ca(OH)(2))rarr B unders...

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  16. CH(3)CHO overset(Na//C(2)H(5)OH)rarr X underset(170^(@)C)overset(conc....

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  17. CH(3)CHO overset(HCN)rarr X underset(H^(+))overset(H(2)O)rarrY. What a...

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  18. CH(4) underset(hv)overset(Cl(2))rarr A overset(Na)rarr B underset(hv)o...

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  19. CH -= CH underset(1% HgSO(4))overset(50% H(2)SO(4))rarr A underset("di...

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  20. HCHO underset(Ni)overset(H(2))rarr A overset(PCl(5))rarr B underset(KC...

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