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Why S(N^(1)) reactions are favourable in...

Why `S_(N^(1))` reactions are favourable in polar solvents?

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S_N2 reactions are

Aliphatic nucleophilic substitution mainly takes place by two mechanisms (i.e) SN^1 & SN^2 Primary halides mainly undergo by SN^2 mechanism and are favourable in polar aprotic solvents. SN^1 reactions takes place mainly by tertiary halide and are more favourable in polar protic solvents, In case of tertiary halides, E_1 comes competition to SN^1 reaction. Keeping in view of these general points, answer the following questions (+)C_6H_5CH(CH_3)Cl to (pm) C_6H_5CH(OH)CH_3 in which of the following solvents, the above reaction is most favourable

Aliphatic nucleophilic substitution mainly takes place by two mechanisms (i.e) SN^1 & SN^2 Primary halides mainly undergo by SN^2 mechanism and are favourable in polar aprotic solvents. SN^1 reactions takes place mainly by tertiary halide and are more favourable in polar protic solvents, In case of tertiary halides, E_1 comes competition to SN^1 reaction. Keeping in view of these general points, answer the following questions Which of the following reactions, the reactions takes place by SN^1 mechanism mainly.

Which type of compounds are more soluble in polar solvents ?

Which of the following compounds under goes predominantly S_N2 reaction with a NaOH in polar aprotic solveats

Predict the order of reactivity of the following compounds in S_(n^(1)) and S_(N^(2)) reactions : The four isomeric bromobutanes,

Acrylic paints are soluble in: a) polar solvents b) non-polar solvents

Predict the order of reactivity of the compounds in S_(N)1 and S_(N) 2 reactions . The four isomeric bromobutanes

(A): S_(N^(2)) reaction takes place in single step. (R): S_(N^(2)) reaction involves the reactivity order of alkyl halides as 1^@ gt 2^@ gt 3^@ halides.

SN^2 reactions of alkyl halides is a bimolecular reaction which take place through formation of a transition state. The rate of reaction depends on the concentration of alkyl halide and nucleophile.The reaction is favoured by strong nucleophlie in polar aprotic solvents. In which of the following solvents SN^2 reaction is more favourable

AAKASH SERIES-ALKYL AND ARYL HALIDES-Exercise-1.2
  1. Give the nucleophilic substitution mechanism with allylic and benzylic...

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  2. What happends when an optically active alkyl halide undergoes nuceloph...

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  3. Why S(N^(1)) reactions are favourable in polar solvents?

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  4. Differentiate between nucleophilicity and basicity with suitable examp...

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  5. Explain Saytzeff rule with suitable examples

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  6. Write a note on elimination reactions of alkyl halides

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  7. How the formation of poisonous phosgene can be prevented from chlorofo...

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  8. What are the consequences when human beings are exposed to carbon tetr...

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  9. In aqueous potassium hydroxide nucleophilic substitution takes place, ...

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  10. Discuss the effect of the nucleophile and substrate on the mechanism o...

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  11. Which test is useful to distinguish between 2-pentanone and 3-pentanon...

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  12. Electron withdrawing groups in benzene ring facilitate nucleophilic su...

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  13. What are the disadvantages of freons?

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  14. Give the IUPAC name of D.D.T why is it banned in some countries?

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  15. Give the equation for the formation of chlorobenzene by Raschig method...

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  16. Halogen atom present in benzene ring is ortho, para directing, but dea...

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  17. Predict the product(s) of the following reaction

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  18. Tertiary halides mainly undergo elimination rather than substitution. ...

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  19. CH(3)CH(2)CH(2)OH overset(PBr(3))rarr A underset(KOH)overset("alcoholi...

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  20. (CH(3))(3)C C(CH(3))(3) overset(Na,"ether")rarr R'-X overset(Mg)rarr D...

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