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A cubic solid is made up of two elements...

A cubic solid is made up of two elements P and Q . Atoms of P are present at the corners of the cube and atoms of Q are present at body centre. What is the formula of the compound and what are coordination numbers of P and Q ?

A

`PQ_2`, 6:6

B

PQ,6:6

C

`P_2Q`,6:6

D

PQ,8:8

Text Solution

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The correct Answer is:
To solve the problem, we need to determine the formula of the compound formed by elements P and Q, as well as their coordination numbers based on their positions in the cubic solid. ### Step 1: Calculate the number of atoms of P Atoms of P are located at the corners of the cube. In a cube, there are 8 corners, and each corner atom is shared among 8 adjacent cubes. Therefore, the contribution of each corner atom to the cube is \( \frac{1}{8} \). - Total contribution from P: \[ \text{Total atoms of P} = 8 \text{ corners} \times \frac{1}{8} = 1 \] ### Step 2: Calculate the number of atoms of Q Atoms of Q are located at the body center of the cube. There is only one body center in a cube, and it is not shared with any other cube. - Total contribution from Q: \[ \text{Total atoms of Q} = 1 \] ### Step 3: Determine the formula of the compound Now that we have the total number of atoms for both elements, we can write the formula of the compound. - The formula of the compound is: \[ \text{Formula} = P^1Q^1 = PQ \] ### Step 4: Calculate the coordination numbers The coordination number is defined as the number of nearest neighbors surrounding an atom. - For atom P: In this structure, each atom of P at the corners is surrounded by the atoms of Q at the body center. Since there is one body center atom and it is surrounded by 8 corner atoms, the coordination number of P is 8. - For atom Q: Each atom of Q at the body center is surrounded by the 8 corner atoms of P. Thus, the coordination number of Q is also 8. ### Final Answer - The formula of the compound is \( PQ \). - The coordination numbers are: - Coordination number of P = 8 - Coordination number of Q = 8

To solve the problem, we need to determine the formula of the compound formed by elements P and Q, as well as their coordination numbers based on their positions in the cubic solid. ### Step 1: Calculate the number of atoms of P Atoms of P are located at the corners of the cube. In a cube, there are 8 corners, and each corner atom is shared among 8 adjacent cubes. Therefore, the contribution of each corner atom to the cube is \( \frac{1}{8} \). - Total contribution from P: \[ \text{Total atoms of P} = 8 \text{ corners} \times \frac{1}{8} = 1 ...
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