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The edge length of a face centred unit c...

The edge length of a face centred unit cubic cell is 508 pm. If the radius of cation is 110 pm, the radius of anion will be

A

110 pm

B

220 pm

C

285 pm

D

144 pm

Text Solution

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The correct Answer is:
To find the radius of the anion in a face-centered cubic (FCC) unit cell, we can follow these steps: ### Step-by-Step Solution: 1. **Understand the Structure of FCC Unit Cell**: - In a face-centered cubic (FCC) unit cell, atoms are located at each of the eight corners and at the centers of each of the six faces of the cube. 2. **Identify the Given Values**: - Edge length of the unit cell (a) = 508 pm - Radius of cation (r_cation) = 110 pm 3. **Establish the Relationship**: - In an FCC unit cell, the relationship between the edge length (a), the radius of the cation (r_cation), and the radius of the anion (r_anion) can be expressed as: \[ a = 2 \times r_{cation} + 2 \times r_{anion} \] 4. **Substitute the Known Values**: - Substitute the known values into the equation: \[ 508 = 2 \times 110 + 2 \times r_{anion} \] 5. **Simplify the Equation**: - Calculate \(2 \times 110\): \[ 2 \times 110 = 220 \] - Now, substitute this back into the equation: \[ 508 = 220 + 2 \times r_{anion} \] 6. **Isolate the Term with r_anion**: - Rearranging the equation gives: \[ 2 \times r_{anion} = 508 - 220 \] - Calculate \(508 - 220\): \[ 508 - 220 = 288 \] 7. **Solve for r_anion**: - Now, divide both sides by 2 to find the radius of the anion: \[ r_{anion} = \frac{288}{2} = 144 \text{ pm} \] 8. **Final Answer**: - The radius of the anion is **144 pm**.

To find the radius of the anion in a face-centered cubic (FCC) unit cell, we can follow these steps: ### Step-by-Step Solution: 1. **Understand the Structure of FCC Unit Cell**: - In a face-centered cubic (FCC) unit cell, atoms are located at each of the eight corners and at the centers of each of the six faces of the cube. 2. **Identify the Given Values**: ...
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