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The fraction of total volume occupied by...

The fraction of total volume occupied by the atom present in a simple cubic is

A

`pi/4`

B

`pi/6`

C

`pi/(3sqrt2)`

D

`pi/(4sqrt2)`

Text Solution

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The correct Answer is:
To find the fraction of total volume occupied by the atoms present in a simple cubic structure, we can follow these steps: ### Step-by-Step Solution: 1. **Understanding the Simple Cubic Structure**: - In a simple cubic lattice, atoms are located at the corners of the cube. - Each corner atom is shared by 8 adjacent cubes. 2. **Calculating the Total Number of Atoms**: - Since there is one atom at each of the 8 corners, the total contribution of atoms per cube is: \[ \text{Total atoms} = 8 \times \frac{1}{8} = 1 \text{ atom} \] 3. **Volume of One Atom**: - The volume of a single atom (considering it as a sphere) is given by: \[ V_{\text{atom}} = \frac{4}{3} \pi r^3 \] - Here, \( r \) is the radius of the atom. 4. **Relating Edge Length and Radius**: - In a simple cubic structure, the edge length \( a \) of the cube is related to the radius \( r \) of the atom by: \[ a = 2r \] - Therefore, we can express \( r \) in terms of \( a \): \[ r = \frac{a}{2} \] 5. **Volume of the Cube**: - The volume of the cube is given by: \[ V_{\text{cube}} = a^3 \] 6. **Substituting for Volume of Atom**: - Substitute \( r = \frac{a}{2} \) into the volume of the atom: \[ V_{\text{atom}} = \frac{4}{3} \pi \left(\frac{a}{2}\right)^3 = \frac{4}{3} \pi \frac{a^3}{8} = \frac{4}{24} \pi a^3 = \frac{\pi a^3}{6} \] 7. **Calculating the Fraction of Volume Occupied**: - The fraction of the total volume occupied by the atom is: \[ \text{Fraction} = \frac{V_{\text{atom}}}{V_{\text{cube}}} = \frac{\frac{\pi a^3}{6}}{a^3} \] - Simplifying this gives: \[ \text{Fraction} = \frac{\pi}{6} \] ### Final Answer: The fraction of total volume occupied by the atom present in a simple cubic structure is: \[ \frac{\pi}{6} \]
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