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A metal crystallises in a bcc lattice ,i...

A metal crystallises in a bcc lattice ,its unit cell edge length in about `300` pm and its molar mass is about `50g mol^(-1)` what would be the density of the metal (in g `cm^(-3))`?

A

`"10 g cm"^(-3)`

B

`" 14.2 g cm"^(-3)`

C

`"6.15 g cm"^(-3)`

D

`"9.32 g cm"^(-3)`

Text Solution

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The correct Answer is:
To find the density of a metal that crystallizes in a body-centered cubic (BCC) lattice, we can use the formula for density: \[ \rho = \frac{Z \cdot M}{N_A \cdot a^3} \] Where: - \(\rho\) = density of the metal (g/cm³) - \(Z\) = number of atoms per unit cell (for BCC, \(Z = 2\)) - \(M\) = molar mass of the metal (g/mol) - \(N_A\) = Avogadro's number (\(6.022 \times 10^{23} \text{ mol}^{-1}\)) - \(a\) = edge length of the unit cell (cm) ### Step 1: Convert the edge length from picometers to centimeters. Given: - \(a = 300 \text{ pm} = 300 \times 10^{-12} \text{ m} = 300 \times 10^{-10} \text{ cm} = 3.00 \times 10^{-8} \text{ cm}\) ### Step 2: Substitute the values into the density formula. We know: - \(Z = 2\) (for BCC) - \(M = 50 \text{ g/mol}\) - \(N_A = 6.022 \times 10^{23} \text{ mol}^{-1}\) - \(a = 3.00 \times 10^{-8} \text{ cm}\) Now substituting these values into the density formula: \[ \rho = \frac{2 \cdot 50}{6.022 \times 10^{23} \cdot (3.00 \times 10^{-8})^3} \] ### Step 3: Calculate \(a^3\). Calculating \(a^3\): \[ (3.00 \times 10^{-8})^3 = 27.00 \times 10^{-24} \text{ cm}^3 = 2.7 \times 10^{-23} \text{ cm}^3 \] ### Step 4: Substitute \(a^3\) back into the density formula. Now substituting \(a^3\) back into the equation: \[ \rho = \frac{100}{6.022 \times 10^{23} \cdot 2.7 \times 10^{-23}} \] ### Step 5: Calculate the denominator. Calculating the denominator: \[ 6.022 \times 10^{23} \cdot 2.7 \times 10^{-23} = 16.2274 \] ### Step 6: Calculate the density. Now substituting back into the density formula: \[ \rho = \frac{100}{16.2274} \approx 6.15 \text{ g/cm}^3 \] ### Final Answer: Thus, the density of the metal is approximately **6.15 g/cm³**. ---

To find the density of a metal that crystallizes in a body-centered cubic (BCC) lattice, we can use the formula for density: \[ \rho = \frac{Z \cdot M}{N_A \cdot a^3} \] Where: - \(\rho\) = density of the metal (g/cm³) ...
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