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Which of the following shows nitrogen wi...

Which of the following shows nitrogen with its increasing order of oxidation number.

A

`N_(2)O lt NO lt NO_(2) lt NO_(3)^(-) lt NH_(4)^(+)`

B

`NH_(4)^(+) lt N_(2)O lt NO lt NO_(2) lt NO_(3)^(-)`

C

`NH_(4)^(+) lt N_(2)O lt NO_(2) lt NO_(3)^(-) lt NO`

D

`NH_(4)^(+) lt NO lt N_(2)O lt NO_(2) lt NO_(3)^(-)`

Text Solution

AI Generated Solution

The correct Answer is:
To determine the increasing order of oxidation numbers of nitrogen in the given compounds, we will calculate the oxidation number of nitrogen in each compound step by step. ### Step 1: Calculate the oxidation number for N2O 1. Let the oxidation number of nitrogen be \( X \). 2. The oxidation number of oxygen is \(-2\). 3. The equation for the compound N2O is: \[ 2X + (-2) = 0 \] 4. Simplifying this gives: \[ 2X - 2 = 0 \implies 2X = 2 \implies X = +1 \] Therefore, the oxidation number of nitrogen in N2O is **+1**. ### Step 2: Calculate the oxidation number for NO 1. Let the oxidation number of nitrogen be \( X \). 2. The oxidation number of oxygen is \(-2\). 3. The equation for the compound NO is: \[ X + (-2) = 0 \] 4. Simplifying this gives: \[ X - 2 = 0 \implies X = +2 \] Therefore, the oxidation number of nitrogen in NO is **+2**. ### Step 3: Calculate the oxidation number for NO2 1. Let the oxidation number of nitrogen be \( X \). 2. The oxidation number of oxygen is \(-2\). 3. The equation for the compound NO2 is: \[ X + 2(-2) = 0 \] 4. Simplifying this gives: \[ X - 4 = 0 \implies X = +4 \] Therefore, the oxidation number of nitrogen in NO2 is **+4**. ### Step 4: Calculate the oxidation number for NH4+ 1. Let the oxidation number of nitrogen be \( X \). 2. The oxidation number of hydrogen is \( +1 \) and there are 4 hydrogen atoms. 3. The equation for the ion NH4+ is: \[ X + 4(+1) = +1 \] 4. Simplifying this gives: \[ X + 4 = 1 \implies X = 1 - 4 \implies X = -3 \] Therefore, the oxidation number of nitrogen in NH4+ is **-3**. ### Step 5: Calculate the oxidation number for NO3- 1. Let the oxidation number of nitrogen be \( X \). 2. The oxidation number of oxygen is \(-2\) and there are 3 oxygen atoms. 3. The equation for the ion NO3- is: \[ X + 3(-2) = -1 \] 4. Simplifying this gives: \[ X - 6 = -1 \implies X = -1 + 6 \implies X = +5 \] Therefore, the oxidation number of nitrogen in NO3- is **+5**. ### Summary of Oxidation Numbers: - N2O: +1 - NO: +2 - NO2: +4 - NH4+: -3 - NO3-: +5 ### Step 6: Arrange in increasing order Now, we can arrange the oxidation numbers in increasing order: - NH4+: -3 - N2O: +1 - NO: +2 - NO2: +4 - NO3-: +5 Thus, the increasing order of oxidation numbers of nitrogen is: **NH4+ < N2O < NO < NO2 < NO3-** ### Final Answer: The correct answer is option **2** (if that corresponds to the increasing order derived).

To determine the increasing order of oxidation numbers of nitrogen in the given compounds, we will calculate the oxidation number of nitrogen in each compound step by step. ### Step 1: Calculate the oxidation number for N2O 1. Let the oxidation number of nitrogen be \( X \). 2. The oxidation number of oxygen is \(-2\). 3. The equation for the compound N2O is: \[ 2X + (-2) = 0 ...
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Knowledge Check

  • Which of the following shows oxidation of reactant.

    A
    1
    B
    1, 2
    C
    `1, 2, 3`
    D
    All of these
  • Which of the following arrangements represent increaseing oxidation number of the central atom?

    A
    `CrO_(2)^(-),ClO_(3)^(-),CrO_(4)^(2-),MnO_(4)^(-)`
    B
    `ClO_(3)^(-),CrO_(4)^(2-),MnO_(4)^(-),CrO_(2)^(-)`
    C
    `CrO_(2)^(-),ClO_(3)^(-),MNO_(4)^(-),CrO_(4)^(2-)`
    D
    `CrO_(4)^(2-),MnO_(4)^(-),CrO_(2)^(-),ClO_(3)^(-)`
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