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Consider the following sequence of conve...

Consider the following sequence of conversion.
`underset((X))ubrace(2NO+O_(2)) Leftrightarrow underset((Y))(2NO_(2)) underset("heat")overset("cool")Leftrightarrow underset((Z))(N_(2)O_(4))`
X, Y and Z can be described as

A

1. `{:("X","Y","Z"),("Colourless","Brown paramagnetic"," Colourless diamagnetic"):}`

B

2. `{:("X","Y","Z"),("Brown","Colourless diamagnetic","Brown paramagnetic"):}`

C

3. `{:("X","Y","Z"),("Colourless","Colourless, paramagnetic","Brown diamagnetic"):}`

D

4. `{:("X","Y","Z"),("Brown","Brown paramagnetic","Brown diamagnetic"):}`

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AI Generated Solution

The correct Answer is:
To solve the problem, we will analyze the sequence of conversions provided and characterize the substances X, Y, and Z based on their properties. ### Step-by-step Solution: 1. **Identify the substances:** - The first substance (X) is formed from the reaction of nitrogen monoxide (NO) and oxygen (O2). The reaction is: \[ 2NO + O_2 \rightarrow 2NO_2 \] - The second substance (Y) is nitrogen dioxide (NO2), which is produced from the reaction above. - The third substance (Z) is dinitrogen tetroxide (N2O4), which is formed from the cooling of NO2: \[ 2NO_2 \leftrightarrow N_2O_4 \] 2. **Characterize Substance X (NO):** - Nitric oxide (NO) is a colorless gas. It is a free radical with an unpaired electron, which makes it paramagnetic. 3. **Characterize Substance Y (NO2):** - Nitrogen dioxide (NO2) is a brown gas. It is also an odd-electron molecule, meaning it has an unpaired electron, which contributes to its paramagnetic nature. 4. **Characterize Substance Z (N2O4):** - Dinitrogen tetroxide (N2O4) is a dimer of NO2. It is colorless and is diamagnetic because it has no unpaired electrons. 5. **Summarize the characteristics:** - **X (NO)**: Colorless, paramagnetic - **Y (NO2)**: Brown, paramagnetic - **Z (N2O4)**: Colorless, diamagnetic 6. **Conclusion:** - Based on the properties identified, we can describe X, Y, and Z as follows: - X: Colorless, paramagnetic (NO) - Y: Brown, paramagnetic (NO2) - Z: Colorless, diamagnetic (N2O4) ### Final Answer: - X is colorless and paramagnetic (NO), Y is brown and paramagnetic (NO2), and Z is colorless and diamagnetic (N2O4).

To solve the problem, we will analyze the sequence of conversions provided and characterize the substances X, Y, and Z based on their properties. ### Step-by-step Solution: 1. **Identify the substances:** - The first substance (X) is formed from the reaction of nitrogen monoxide (NO) and oxygen (O2). The reaction is: \[ 2NO + O_2 \rightarrow 2NO_2 ...
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NCERT FINGERTIPS ENGLISH-THE P-BLOCK ELEMENTS -Assertion And Reason
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  2. Assertion : The covalence of nitrogen in N(2)O(5) is 5 Reason : Nitr...

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  3. Assertion : Catenation tendency is weaker in nitrogen. Reason : Nitr...

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  4. Assertion: Ammonia acts as a ligand. Reason : A lone pair of electro...

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  5. Assertion : White phosphorus is more reactive than red phosphorus. R...

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  6. Assertion : In trigonal bipyramidal structure two axial bonds are long...

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  7. Assertion : Acidic character of group 16 hydrides increases from H(2)O...

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  8. Assertion : Ozone layer in the upper region of atmosphere protects ear...

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  9. Assertion : O(3) acts as a powerful oxidising agent. Reason : O(3) o...

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  10. Assertion: In vapour state sulphur is paramagnetic in nature. Reason...

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  11. Assertion : Sulphuric acid reacts with sodium chloride in the followin...

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  12. Assertion : Fluorine combines with sulphur to form SF(6) but no other ...

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  13. Assertion : Fluorine oxidises water to oxygen whereas chlorine and bro...

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  14. Assertion: HClO(4) is a stronger acid than HClO(3). Reason: Oxidatio...

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  15. Assertion : Interhalogen compounds are more reactive than halogens (ex...

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  16. Assertion :Solubility of noble gases in water decreases with increases...

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