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Which of the following increasing order ...

Which of the following increasing order is not correct as mentioned in the property with it?

A

`HCIO lt HClO_(2) lt HClO_(3) lt HClO_(4)` (thermal stability)

B

`HClO_(4) lt HClO_(3) lt HClO_(2) lt HCIO` (oxidising power)

C

`F^(-) lt Cl^(-)lt Br^(-)lt I^(-)` (reducing nature)

D

`HIO_(4) lt ICl lt I_(2) lt HI` (oxidation number of iodine)

Text Solution

AI Generated Solution

The correct Answer is:
To solve the question regarding the incorrect increasing order of properties related to the p-block elements, we will analyze each option provided in the question step by step. ### Step-by-Step Solution: 1. **Understanding Thermal Stability**: - Thermal stability is directly proportional to the oxidation state of the central atom. - For example, consider the series: HClO, HClO2, HClO3, HClO4. - Oxidation states: +1 (HClO), +3 (HClO2), +5 (HClO3), +7 (HClO4). - As the oxidation state increases, the thermal stability also increases. Thus, this order is correct. 2. **Analyzing Oxidizing Power**: - Oxidizing power is inversely proportional to the oxidation number. - For the same series: HClO4, HClO3, HClO2, HClO. - Oxidation states: +7 (HClO4), +5 (HClO3), +3 (HClO2), +1 (HClO). - As the oxidation state decreases, the oxidizing power increases. Thus, this order is also correct. 3. **Reducing Nature**: - Reducing power increases down the group in the periodic table. - For halides: F-, Cl-, Br-, I-. - I- has the strongest reducing power, followed by Br-, Cl-, and F-. - This order is correct as well. 4. **Oxidizing Nature of Iodine**: - Calculate the oxidation states for the following: - HIO4: +7 (Iodine) - ICl: +1 (Iodine) - I2: 0 (Iodine) - HI: -1 (Iodine) - The oxidation states are: +7 (HIO4), +1 (ICl), 0 (I2), -1 (HI). - The order of increasing oxidation state is from +7 to -1, which is incorrect as it suggests a decrease in oxidation state from HIO4 to HI. - Therefore, this order is incorrect. ### Conclusion: The incorrect increasing order is related to the oxidizing nature of iodine, specifically the oxidation states from HIO4 to HI. Thus, the answer is option 4.

To solve the question regarding the incorrect increasing order of properties related to the p-block elements, we will analyze each option provided in the question step by step. ### Step-by-Step Solution: 1. **Understanding Thermal Stability**: - Thermal stability is directly proportional to the oxidation state of the central atom. - For example, consider the series: HClO, HClO2, HClO3, HClO4. - Oxidation states: +1 (HClO), +3 (HClO2), +5 (HClO3), +7 (HClO4). ...
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