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The oxidation state of central atom in t...

The oxidation state of central atom in the anion of compound `NaH_(2)PO_(2)` will be . . . . . . . . .

A

`+3`

B

`+5`

C

`+1`

D

`-3`

Text Solution

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The correct Answer is:
To find the oxidation state of the central atom (phosphorus) in the anion of the compound NaH₂PO₂, we can follow these steps: ### Step 1: Identify the Anion The compound NaH₂PO₂ dissociates into Na⁺ and the anion H₂PO₂⁻. We need to focus on the anion H₂PO₂⁻. ### Step 2: Assign Oxidation States In the anion H₂PO₂⁻: - The oxidation state of hydrogen (H) is +1. - The oxidation state of oxygen (O) is -2. ### Step 3: Set Up the Equation Let the oxidation state of phosphorus (P) be x. The overall charge of the anion H₂PO₂⁻ is -1. Therefore, we can set up the following equation based on the sum of oxidation states: \[ \text{Total oxidation state} = \text{Oxidation state of H} + \text{Oxidation state of P} + \text{Oxidation state of O} \] This can be expressed as: \[ 2(+1) + x + 2(-2) = -1 \] ### Step 4: Simplify the Equation Now, simplify the equation: \[ 2 + x - 4 = -1 \] This simplifies to: \[ x - 2 = -1 \] ### Step 5: Solve for x Now, solve for x: \[ x = -1 + 2 \] \[ x = +1 \] ### Conclusion The oxidation state of phosphorus (the central atom) in the anion H₂PO₂⁻ is +1. Thus, the answer is **+1**.
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