Home
Class 12
CHEMISTRY
Assertion : Glucose reacts with phenyl h...

Assertion `:` Glucose reacts with phenyl hydrazine and Fehling's solution but not with `NaHSO_(3)`.
Reason`:` `NaHSO_(3)` cannot break the ring structure.

A

If both assertion and reason are true and reason is the correct explanation of assertion.

B

If both assertion and reason are true but reason is not the correct explanation of assertion.

C

If assertion is true but reason is false.

D

If both assertion and reason are false.

Text Solution

AI Generated Solution

The correct Answer is:
To solve the question, we need to analyze both the assertion and the reason provided. ### Step-by-Step Solution: 1. **Understanding the Assertion**: - The assertion states that glucose reacts with phenyl hydrazine and Fehling's solution but does not react with NaHSO₃ (sodium bisulfite). - Glucose is a monosaccharide that contains both an aldehyde group and alcoholic (hydroxyl) groups. 2. **Reactions of Glucose**: - **With Phenyl Hydrazine**: Glucose can react with phenyl hydrazine to form a hydrazone. This reaction occurs because glucose has an aldehyde functional group, which is reactive towards phenyl hydrazine. - **With Fehling's Solution**: Fehling's solution is used to test for reducing sugars. Glucose, being a reducing sugar due to its aldehyde group, will react with Fehling's solution, resulting in a color change. - **With NaHSO₃**: Sodium bisulfite typically reacts with free aldehyde groups to form bisulfite addition products. However, in the case of glucose, the aldehyde group is involved in a cyclic structure (pyranose form), and thus it is not free to react. 3. **Understanding the Reason**: - The reason states that NaHSO₃ cannot break the ring structure of glucose. - This is true because the cyclic form of glucose (pyranose) does not have a free aldehyde group available for reaction with NaHSO₃. The ring structure prevents the formation of the bisulfite addition product. 4. **Conclusion**: - Both the assertion and the reason are true. - The reason provided correctly explains why glucose does not react with NaHSO₃, which is due to the presence of the cyclic structure that does not allow for the free aldehyde group to participate in the reaction. ### Final Answer: Both assertion and reason are true, and the reason is the correct explanation of the assertion.

To solve the question, we need to analyze both the assertion and the reason provided. ### Step-by-Step Solution: 1. **Understanding the Assertion**: - The assertion states that glucose reacts with phenyl hydrazine and Fehling's solution but does not react with NaHSO₃ (sodium bisulfite). - Glucose is a monosaccharide that contains both an aldehyde group and alcoholic (hydroxyl) groups. ...
Promotional Banner

Topper's Solved these Questions

  • BIOMOLECULES

    NCERT FINGERTIPS ENGLISH|Exercise Carbohydrates|35 Videos
  • BIOMOLECULES

    NCERT FINGERTIPS ENGLISH|Exercise Proteins|30 Videos
  • BIOMOLECULES

    NCERT FINGERTIPS ENGLISH|Exercise EXEMPLER PROBLEMS|16 Videos
  • AMINES

    NCERT FINGERTIPS ENGLISH|Exercise ASSERTION & REASON CORNER|14 Videos
  • CHEMICAL KINETICS

    NCERT FINGERTIPS ENGLISH|Exercise Assertion And Reason|15 Videos

Similar Questions

Explore conceptually related problems

Glucose reacts with HNO_(3) to form

Benzophenone does not react with NaHSO_(3) . Explain.

What happen when : Ethanal is treated with NaHSO_(3) .

Which of the following compounds does not react with NaHSO_(3) ?

Describe the action of heat on NaHSO_(3)

Assertion : Chloral reacts with phenyl chloride to form DDT. Reason : It is an electrophilic substitution reaction.

How does acetaldehyde react with: NaHSO_(3)

Assertion: (CH_(3))_(3)C COC(CH_(3))_(3) and acetone can be distanguished by the reaction with NaHSO_(3) . Reason : HSO_(3) is the nucleophile in bisulphite addition.

Assertion: Boron reacts with HNO_(3) Reason: Boron reacts with all acids.

Draw structure NaHSO_(3)