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Arrange the following metals in increas...

Arrange the following metals in increasing order of their reducing power.
`E_(K^(+)//K)^(@)=-2.93V, E_(Ag^(+)//Ag)^(@)=+0.80V, E_(Al^(3)//Al)^(@)=-1.66V E_(Au^(3+)//Au)^(@)=+1.40 V,
E_(Li^(+)//Li)^(@)=-3.05 V`

A

`Li lt K lt Al lt Ag lt Au`

B

`Au lt Ag lt Al lt K lt Li`

C

`K lt Al lt Au lt Ag lt Li`

D

`Al lt Ag lt Au lt Li lt K`

Text Solution

Verified by Experts

The correct Answer is:
B

Lower the electrode potential, better is the reducing power. The electrode potential increases in the order of `Li^(+)//Li (-3.05 V), K^(+)//K (-2.93 V), Al^(3+)//Al, (-1.66 V), Ag^(+)//Ag (+0.80 V) ` and `Au^(3+)//Au (+1.40 V)`. Hence, reducing power of metals will be `Au lt Ag lt Al lt K lt Li`.
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  19. Fluorine is the best oxidising agent because it has

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