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On moving from left to right in a period...

On moving from left to right in a period what is the order of acidic character of hydrides ?

A

`NH_(3) lt H_(2)O lt HF`

B

`HF lt H_(2)O lt NH_(3)`

C

`H_(2)O lt HF lt NH_(3)`

D

`H_(2)O lt NH_(3) lt HF`

Text Solution

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The correct Answer is:
To determine the order of acidic character of hydrides as we move from left to right in a period, we will analyze the hydrides of nitrogen (NH3), oxygen (H2O), and fluorine (HF). The acidic character of these hydrides is related to their ability to donate a proton (H⁺) and the stability of their conjugate bases after the proton is removed. ### Step-by-Step Solution: 1. **Identify the Hydrides**: We are considering the hydrides of nitrogen (NH3), oxygen (H2O), and fluorine (HF). 2. **Understanding Acidic Character**: The acidic character of a compound is defined by its ability to donate a proton (H⁺). The more stable the conjugate base formed after the donation of H⁺, the stronger the acid. 3. **Conjugate Bases Formation**: - For NH3 (ammonia), the conjugate base formed is NH2⁻ (amide ion). - For H2O (water), the conjugate base formed is OH⁻ (hydroxide ion). - For HF (hydrofluoric acid), the conjugate base formed is F⁻ (fluoride ion). 4. **Stability of Conjugate Bases**: The stability of the conjugate bases is influenced by the electronegativity of the atoms involved: - F⁻ is more stable due to fluorine's high electronegativity. - OH⁻ is less stable than F⁻ but more stable than NH2⁻. - NH2⁻ is the least stable among the three. 5. **Order of Stability of Conjugate Bases**: Based on the stability of the conjugate bases: - F⁻ > OH⁻ > NH2⁻ 6. **Order of Acidic Character**: Since the acidic strength is directly proportional to the stability of the conjugate base, we can conclude: - HF > H2O > NH3 ### Final Answer: The order of acidic character of the hydrides from left to right in the period is: **HF > H2O > NH3**

To determine the order of acidic character of hydrides as we move from left to right in a period, we will analyze the hydrides of nitrogen (NH3), oxygen (H2O), and fluorine (HF). The acidic character of these hydrides is related to their ability to donate a proton (H⁺) and the stability of their conjugate bases after the proton is removed. ### Step-by-Step Solution: 1. **Identify the Hydrides**: We are considering the hydrides of nitrogen (NH3), oxygen (H2O), and fluorine (HF). 2. **Understanding Acidic Character**: The acidic character of a compound is defined by its ability to donate a proton (H⁺). The more stable the conjugate base formed after the donation of H⁺, the stronger the acid. ...
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