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which of the following is an electrophil...

which of the following is an electrophilic reagent?

A

`H_(2)O`

B

`NH_(3)`

C

`OH^(-)`

D

`Cl^+`

Text Solution

AI Generated Solution

The correct Answer is:
To determine which of the given options is an electrophilic reagent, we need to understand what an electrophile is. An electrophile is a species that is electron-deficient and can accept electrons from a nucleophile (an electron-rich species). Let's analyze each option step by step: ### Step 1: Analyze Option 1 - Water (H2O) - **Structure**: Water has a bent structure with oxygen bonded to two hydrogen atoms. - **Electron Count**: Oxygen has 6 valence electrons and forms two bonds with hydrogen, leaving it with two lone pairs (4 electrons). - **Conclusion**: Water has an abundance of electrons due to its lone pairs and does not attract more electrons. Therefore, it is not an electrophile; it acts as a nucleophile. ### Step 2: Analyze Option 2 - Ammonia (NH3) - **Structure**: Ammonia has a trigonal pyramidal shape with nitrogen bonded to three hydrogen atoms. - **Electron Count**: Nitrogen has 7 valence electrons and forms three bonds with hydrogen, leaving it with one lone pair (2 electrons). - **Conclusion**: Similar to water, ammonia has a lone pair of electrons and does not seek additional electrons. Thus, it is not an electrophile; it is also a nucleophile. ### Step 3: Analyze Option 3 - Hydroxide Ion (OH⁻) - **Structure**: The hydroxide ion consists of an oxygen atom bonded to a hydrogen atom with an extra electron due to the negative charge. - **Electron Count**: Oxygen has 6 valence electrons. The negative charge adds one more electron, giving it a total of 8 electrons (4 pairs). - **Conclusion**: The hydroxide ion has an excess of electrons and does not attract more electrons. Therefore, it is not an electrophile; it is a nucleophile. ### Step 4: Analyze Option 4 - Chlorine Ion (Cl⁺) - **Structure**: The chlorine ion has a positive charge. - **Electron Count**: Chlorine normally has 7 valence electrons, but the positive charge indicates it is electron-deficient. - **Conclusion**: The positive charge on chlorine means it is seeking electrons to stabilize itself. Therefore, it is an electrophile. ### Final Answer: Based on the analysis, the correct answer is **Option 4: Chlorine Ion (Cl⁺)**, as it is the only electrophilic reagent among the options provided. ---

To determine which of the given options is an electrophilic reagent, we need to understand what an electrophile is. An electrophile is a species that is electron-deficient and can accept electrons from a nucleophile (an electron-rich species). Let's analyze each option step by step: ### Step 1: Analyze Option 1 - Water (H2O) - **Structure**: Water has a bent structure with oxygen bonded to two hydrogen atoms. - **Electron Count**: Oxygen has 6 valence electrons and forms two bonds with hydrogen, leaving it with two lone pairs (4 electrons). - **Conclusion**: Water has an abundance of electrons due to its lone pairs and does not attract more electrons. Therefore, it is not an electrophile; it acts as a nucleophile. ...
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