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Which one of the following acids would y...

Which one of the following acids would you expect to be the strongest?

A

`I-CH_(2)COOH`

B

`Cl-CH_(2)COOH`

C

`Br-CH_(2)COOH`

D

`F-CH_(2)COOH`

Text Solution

AI Generated Solution

The correct Answer is:
To determine which of the given acids is the strongest, we need to analyze the stability of the anions formed when these acids donate a proton (H+). The stronger the acid, the more stable the anion it forms. ### Step-by-Step Solution: 1. **Identify the Acids**: Let's assume the acids in question are represented as follows: - Acid A: RCOOH (with a substituent that has a -I effect) - Acid B: RCOOH (with a different substituent that has a -I effect) - Acid C: RCOOH (with another substituent that has a -I effect) - Acid D: RCOOH (with a substituent that has a strong -I effect) 2. **Understand the -I Effect**: The -I (inductive) effect refers to the electron-withdrawing effect of substituents. The more electronegative the substituent, the stronger its -I effect, which stabilizes the negative charge on the anion formed after the acid donates a proton. 3. **Analyze the Substituents**: - Fluorine (F) is the most electronegative element, followed by chlorine (Cl), bromine (Br), and iodine (I). - Therefore, the order of -I effect strength is: F > Cl > Br > I. 4. **Determine Anion Stability**: - When each acid donates a proton (H+), it forms an anion. The stability of this anion is influenced by the substituent's -I effect. - The more stable the anion, the stronger the acid. 5. **Compare the Acids**: - If Acid D has a fluorine substituent, it will create a more stable anion compared to the others with Cl, Br, or I substituents. - Thus, Acid D is expected to be the strongest acid because it forms the most stable anion. 6. **Conclusion**: Based on the analysis, the acid with the substituent that has the strongest -I effect (in this case, fluorine) will be the strongest acid. Therefore, Acid D is the strongest acid among the options provided. ### Final Answer: **The strongest acid is Acid D.**

To determine which of the given acids is the strongest, we need to analyze the stability of the anions formed when these acids donate a proton (H+). The stronger the acid, the more stable the anion it forms. ### Step-by-Step Solution: 1. **Identify the Acids**: Let's assume the acids in question are represented as follows: - Acid A: RCOOH (with a substituent that has a -I effect) - Acid B: RCOOH (with a different substituent that has a -I effect) - Acid C: RCOOH (with another substituent that has a -I effect) ...
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