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Assertion: sp^(3) hybrid carbon atom is ...

Assertion: `sp^(3)` hybrid carbon atom is more electronegative than sp hybrid carbon atom.
Reason: `sp^(3)` hybrid orbitals are more closer to the nucleus.

A

If both assertion and reason are true and reason is the correct explanation of assertion

B

If both assertion and reason are true but reason is not the correct explanation of assertion

C

If assertion is true but reason is false.

D

If both assertion and reason are false.

Text Solution

AI Generated Solution

The correct Answer is:
To solve the question, we need to analyze both the assertion and the reason provided. ### Step-by-Step Solution: 1. **Understanding the Assertion**: - The assertion states that an `sp^3` hybrid carbon atom is more electronegative than an `sp` hybrid carbon atom. - Electronegativity is a measure of an atom's ability to attract and hold onto electrons. 2. **Understanding Hybridization**: - In `sp^3` hybridization, there is 25% `s` character and 75% `p` character. - In `sp` hybridization, there is 50% `s` character and 50% `p` character. 3. **Electronegativity and `s` Character**: - The electronegativity of an atom is directly related to the percentage of `s` character in its hybrid orbitals. - The more `s` character an orbital has, the closer it is to the nucleus, and thus the more electronegative the atom tends to be. 4. **Comparing Electronegativity**: - For `sp^3` hybridized carbon (25% `s` character), it is less electronegative compared to `sp` hybridized carbon (50% `s` character). - Therefore, the assertion is **false** because `sp` hybridized carbon is more electronegative than `sp^3` hybridized carbon. 5. **Understanding the Reason**: - The reason states that `sp^3` hybrid orbitals are closer to the nucleus. - However, since `sp` hybrid orbitals have more `s` character (50% vs. 25%), they are actually closer to the nucleus than `sp^3` hybrid orbitals. 6. **Conclusion**: - Both the assertion and the reason are false. The correct relationship is that `sp` hybrid carbon is more electronegative than `sp^3` hybrid carbon, and `sp` hybrid orbitals are indeed closer to the nucleus than `sp^3` hybrid orbitals. ### Final Answer: Both the assertion and the reason are false.

To solve the question, we need to analyze both the assertion and the reason provided. ### Step-by-Step Solution: 1. **Understanding the Assertion**: - The assertion states that an `sp^3` hybrid carbon atom is more electronegative than an `sp` hybrid carbon atom. - Electronegativity is a measure of an atom's ability to attract and hold onto electrons. ...
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