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The strongest bond is present in...

The strongest bond is present in

A

`Br_(2)`

B

`I_(2)`

C

`Cl_(2)`

D

`F_(2)`

Text Solution

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The correct Answer is:
To determine which bond is the strongest among the halogens (F2, Cl2, Br2, and I2), we will analyze the bond lengths and bond strengths of these diatomic molecules. ### Step-by-Step Solution 1. **Understanding Bond Strength and Bond Length**: - Bond strength is inversely proportional to bond length. This means that as bond length increases, bond strength decreases. 2. **Order of Bond Length**: - The bond lengths of the halogen diatomic molecules can be arranged from shortest to longest: - F2 (Fluorine) < Cl2 (Chlorine) < Br2 (Bromine) < I2 (Iodine) - This indicates that F2 has the shortest bond length, while I2 has the longest bond length. 3. **Analyzing Bond Strength**: - Since bond strength is inversely related to bond length, we can infer the following order of bond strength: - I2 (weakest) < Br2 < Cl2 < F2 (strongest) - However, we need to consider the electron density and lone pair repulsion in these bonds. 4. **Lone Pair Repulsion**: - Fluorine has three lone pairs on each atom, which leads to significant repulsion between them. This high repulsion weakens the F-F bond despite its short length. - Chlorine also has lone pairs, but the repulsion is less intense than that in fluorine due to the larger size of chlorine atoms. 5. **Final Comparison**: - Although F2 has a short bond length, the high repulsion makes it a weak bond. - Cl2 has a longer bond length than F2 but is stronger due to lower lone pair repulsion. - Therefore, the bond strength order is: - Cl2 > F2 > Br2 > I2 6. **Conclusion**: - The strongest bond among the given options is in Cl2 (Chlorine).
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