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SF(4) has shape....

`SF_(4)` has _____shape.

A

T-shape

B

Bent

C

Octahedral

D

see saw

Text Solution

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The correct Answer is:
To determine the shape of SF₄ (sulfur tetrafluoride), we can follow these steps: ### Step 1: Determine the Valence Electrons Sulfur (S) is in group 16 of the periodic table and has 6 valence electrons. Each fluorine (F) atom has 7 valence electrons, and since there are 4 fluorine atoms, they contribute a total of 28 valence electrons (4 × 7 = 28). **Total valence electrons = 6 (from S) + 28 (from 4 F) = 34 valence electrons.** ### Step 2: Draw the Lewis Structure In the Lewis structure of SF₄, sulfur will form single bonds with each of the four fluorine atoms. Each bond uses 2 electrons. Therefore, 4 bonds will use 8 electrons (4 × 2 = 8). **Remaining electrons = 34 - 8 = 26 electrons.** After forming the bonds, the remaining electrons will be placed on the sulfur atom as lone pairs. Since sulfur can expand its octet, it can accommodate more than 8 electrons. ### Step 3: Account for Lone Pairs After forming 4 bonds with fluorine, sulfur will have 2 lone pairs of electrons left. ### Step 4: Determine the Electron Geometry The electron geometry around sulfur can be determined by counting the total number of regions of electron density (bonding pairs + lone pairs). In SF₄, there are: - 4 bonding pairs (from the 4 S-F bonds) - 1 lone pair This gives a total of 5 regions of electron density. ### Step 5: Identify the Molecular Shape The electron geometry for 5 regions of electron density is trigonal bipyramidal. However, the presence of the lone pair affects the molecular shape. The lone pair occupies one of the equatorial positions, leading to a distortion of the shape. The resulting molecular shape is **seesaw**. ### Conclusion Thus, the shape of SF₄ is **seesaw**. ---
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