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The shape of CIF(3) according to VSEPR m...

The shape of `CIF_(3)` according to VSEPR model is

A

planar triangle

B

T-shape

C

tetrahedral

D

square planar

Text Solution

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The correct Answer is:
To determine the shape of CIF₃ (carbon trifluoride) according to the VSEPR (Valence Shell Electron Pair Repulsion) model, we can follow these steps: ### Step 1: Identify the Central Atom The central atom in CIF₃ is carbon (C). ### Step 2: Determine the Valence Electrons Carbon has 4 valence electrons. ### Step 3: Count the Number of Bonds In CIF₃, carbon forms 3 single bonds with three fluorine (F) atoms. ### Step 4: Consider Lone Pairs Since carbon has 4 valence electrons and it uses 3 of them to form bonds with fluorine, there is 1 valence electron left. This lone electron will form a lone pair. ### Step 5: Calculate Hybridization The hybridization can be calculated using the formula: \[ \text{Hybridization} = \text{Number of valence electrons} + \text{Number of monovalent atoms} - \text{Charge} \] In this case: - Number of valence electrons = 4 (from carbon) - Number of monovalent atoms = 3 (from the three fluorine atoms) - Charge = 0 (no cations or anions) So, the calculation is: \[ \text{Hybridization} = 4 + 3 - 0 = 7 \] Since we are considering the number of hybrid orbitals, we divide by 2: \[ \text{Hybridization} = \frac{7}{2} = 3.5 \] However, we consider the effective hybridization based on the number of bonds and lone pairs, which leads us to sp³ hybridization. ### Step 6: Determine the Molecular Geometry With 3 bonded pairs (C-F) and 1 lone pair, the molecular geometry will be determined by the arrangement of these pairs. According to VSEPR theory, the arrangement of 3 bonded pairs and 1 lone pair corresponds to a trigonal pyramidal shape. ### Conclusion The shape of CIF₃ according to the VSEPR model is trigonal pyramidal. ---
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