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Out off N(2)O,SO(2),I(3)^(+),I(3)^(-),H(...

Out off `N_(2)O,SO_(2),I_(3)^(+),I_(3)^(-),H_(2)O,NO_(2)^(-),N_(3)^(-)`, the linear species are:

A

`NO_(2)^(-),I_(3)^(+),H_(2)O`

B

`N_(2)O,I_(3)^(+),N_(3)^(-)`

C

`N_(2)O,I_(3)^(-),N_(3)^(-)`

D

`N_(3)^(-),I_(3)^(-),NO_(2)^(-)`

Text Solution

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The correct Answer is:
To determine which of the given species are linear, we will analyze each one step by step based on their valence electrons and molecular geometry. ### Step 1: Analyze N₂O (Dinitrogen monoxide) 1. **Count the Valence Electrons**: - Nitrogen (N) has 5 valence electrons, and there are 2 nitrogen atoms: \(5 \times 2 = 10\). - Oxygen (O) has 6 valence electrons: \(6\). - Total = \(10 + 6 = 16\) valence electrons. 2. **Determine Electron Pairs**: - Since 16 is greater than 8, we divide by 2 to find the number of electron pairs: \(16 / 2 = 8\) electron pairs. 3. **Hybridization**: - 8 electron pairs correspond to sp hybridization, which indicates a linear shape. ### Step 2: Analyze SO₂ (Sulfur dioxide) 1. **Count the Valence Electrons**: - Sulfur (S) has 6 valence electrons, and there are 2 oxygen atoms: \(6 + (6 \times 2) = 18\) valence electrons. 2. **Determine Electron Pairs**: - Since 18 is greater than 8, we divide by 2: \(18 / 2 = 9\) electron pairs. 3. **Hybridization**: - 9 electron pairs correspond to sp³d hybridization, which does not indicate a linear shape. ### Step 3: Analyze I₃⁻ (Triiodide ion) 1. **Count the Valence Electrons**: - Iodine (I) has 7 valence electrons, and there are 3 iodine atoms: \(7 \times 3 = 21\). - Add 1 for the negative charge: \(21 + 1 = 22\) valence electrons. 2. **Determine Electron Pairs**: - Since 22 is greater than 8, we divide by 8: \(22 / 8 = 2\) with a remainder of 6. - Divide the remainder by 2: \(6 / 2 = 3\). - Total electron pairs = \(2 + 3 = 5\). 3. **Hybridization**: - 5 electron pairs correspond to sp³d hybridization, which indicates a linear shape. ### Step 4: Analyze I₃⁻ (Triiodide ion) again 1. **Count the Valence Electrons**: - As calculated before, I₃⁻ has 22 valence electrons. 2. **Determine Electron Pairs**: - Total electron pairs = 5. 3. **Hybridization**: - The shape is linear due to the presence of 3 lone pairs and 2 bond pairs. ### Step 5: Analyze H₂O (Water) 1. **Count the Valence Electrons**: - Oxygen has 6 valence electrons, and there are 2 hydrogen atoms: \(6 + (1 \times 2) = 8\) valence electrons. 2. **Determine Electron Pairs**: - Total electron pairs = \(8 / 2 = 4\). 3. **Hybridization**: - 4 electron pairs correspond to sp³ hybridization, which does not indicate a linear shape. ### Step 6: Analyze NO₂⁻ (Nitrite ion) 1. **Count the Valence Electrons**: - Nitrogen has 5 valence electrons, and there are 2 oxygen atoms: \(5 + (6 \times 2) = 17\). - Add 1 for the negative charge: \(17 + 1 = 18\) valence electrons. 2. **Determine Electron Pairs**: - Total electron pairs = \(18 / 2 = 9\). 3. **Hybridization**: - 9 electron pairs correspond to sp³d hybridization, which does not indicate a linear shape. ### Step 7: Analyze N₃⁻ (Azide ion) 1. **Count the Valence Electrons**: - Nitrogen has 5 valence electrons, and there are 3 nitrogen atoms: \(5 \times 3 = 15\). - Add 1 for the negative charge: \(15 + 1 = 16\) valence electrons. 2. **Determine Electron Pairs**: - Total electron pairs = \(16 / 2 = 8\). 3. **Hybridization**: - 8 electron pairs correspond to sp hybridization, which indicates a linear shape. ### Summary of Linear Species - The linear species identified are: - N₂O (linear) - I₃⁻ (linear) - N₃⁻ (linear) ### Final Answer The linear species from the given options are: **N₂O, I₃⁻, and N₃⁻.**
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NCERT FINGERTIPS ENGLISH-PRACTICE PAPER 2-Practice Paper 2
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  2. Permanent hardness is due to presence of soluble salts of Mg and Ca in...

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  3. Mark out the correct increasing order of radius.

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  6. Which of the following is according to Boyle's law?

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  7. pH of a 1.0xx10^(-8) M solution of HCl is

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  8. The substance used as a adsorbentt in the column

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  9. Elements of group 14 exhibit oxidation state of

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  10. With rise in temperature, viscosity of a liquid

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  11. Air contains 21% of oxygen by volume. The number of moles of O(2) pres...

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  12. The ratio of average speed of an oxygen molcule to the RMS speed of a ...

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  13. The kinetic enerrgy of 4 mole sof nitrogen gas at 127^(@)C is (R=2" ca...

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  14. Out off N(2)O,SO(2),I(3)^(+),I(3)^(-),H(2)O,NO(2)^(-),N(3)^(-), the li...

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  15. In which of the following ionisation processes, the bond order has inc...

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  16. Which of the following structure is correctly drawn according to funda...

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  17. Back bonding in BF(3) does not afect

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  18. Ammonium carbamate when heated tto 200^(@)C gives a mixture of NH(3) a...

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  19. For the reaction, A((g))+2B((g))hArr 3C((g))+3((g)),K(p)=0.05" atm at ...

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  20. Consider the following reaction, (i) CO(3)^(2-)+H(2)OhArrHCO(3)^(-)+...

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