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For the reaction, A((g))+2B((g))hArr 3C(...

For the reaction, `A_((g))+2B_((g))hArr 3C_((g))+3_((g)),K_(p)=0.05" atm at "1000K`. The value of `K_(c)` is represented by

A

`5xx10^(-4)R`

B

`(5xx10^(-4))/(R)`

C

`5xx10^(-5)R`

D

`(5xx10^(-5))/(R)`

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The correct Answer is:
To find the value of \( K_c \) for the reaction \( A_{(g)} + 2B_{(g)} \rightleftharpoons 3C_{(g)} + D_{(g)} \) given that \( K_p = 0.05 \, \text{atm} \) at \( 1000 \, \text{K} \), we can use the relationship between \( K_p \) and \( K_c \). ### Step-by-Step Solution: 1. **Identify the Reaction and Given Values:** The reaction is: \[ A_{(g)} + 2B_{(g)} \rightleftharpoons 3C_{(g)} + D_{(g)} \] Given: \[ K_p = 0.05 \, \text{atm} \quad \text{at} \quad T = 1000 \, \text{K} \] 2. **Determine the Change in Moles (\( \Delta n \)):** \[ \Delta n = \text{(moles of products)} - \text{(moles of reactants)} \] - Moles of products: \( 3C + 1D = 3 + 1 = 4 \) - Moles of reactants: \( 1A + 2B = 1 + 2 = 3 \) \[ \Delta n = 4 - 3 = 1 \] 3. **Use the Relationship Between \( K_p \) and \( K_c \):** The relationship is given by: \[ K_p = K_c (R T)^{\Delta n} \] Where: - \( R \) (gas constant) = \( 0.0821 \, \text{L atm K}^{-1} \text{mol}^{-1} \) - \( T = 1000 \, \text{K} \) - \( \Delta n = 1 \) 4. **Substituting Values into the Equation:** \[ 0.05 = K_c \times (0.0821 \times 1000)^1 \] \[ 0.05 = K_c \times 82.1 \] 5. **Solving for \( K_c \):** \[ K_c = \frac{0.05}{82.1} \] \[ K_c = 0.000609 \] \[ K_c = 6.09 \times 10^{-4} \, \text{mol/L} \] ### Final Answer: The value of \( K_c \) is approximately \( 6.09 \times 10^{-4} \, \text{mol/L} \).
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