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R-CH=CH-CHO+NH(2)-overset(O)overset("||"...

`R-CH=CH-CHO+NH_(2)-overset(O)overset("||")C-NHNH_(2)overset(H^(+))to X`
(X) in the above reaction is

A

`R-CH=CH-overset(OH)overset(|)(CH)-NH_(2)CONHNH_(2)`

B

`R-CH=CH-CH=N-NH-overset(O)overset("||")C-NH_(2)`

C

`R-CH=NH_(2)CONH_(2)`

D

`R-CH=CH-underset(OH)underset(|)(CH)-NH_(2)COCH=NHNH_(2)`

Text Solution

AI Generated Solution

The correct Answer is:
To determine the product \( X \) from the given reaction, let's break down the steps involved in the reaction of the unsaturated carbonyl compound \( R-CH=CH-CHO \) with the hydrazine derivative \( NH_2-CO-NH-NH_2 \) in the presence of an acid \( H^+ \). ### Step-by-Step Solution: 1. **Identify the Reactants:** - The first reactant is an unsaturated aldehyde, \( R-CH=CH-CHO \). - The second reactant is a hydrazine derivative, \( NH_2-CO-NH-NH_2 \). 2. **Recognize the Functional Groups:** - The aldehyde group \( -CHO \) is electrophilic due to the carbonyl carbon. - The hydrazine derivative contains nitrogen atoms that can act as nucleophiles because they have lone pairs of electrons. 3. **Nucleophilic Attack:** - The nitrogen from the hydrazine derivative will attack the electrophilic carbonyl carbon of the aldehyde. This forms a tetrahedral intermediate. 4. **Formation of Tetrahedral Intermediate:** - The nucleophilic attack leads to the formation of a tetrahedral intermediate where the carbonyl oxygen becomes negatively charged. 5. **Proton Transfer:** - A proton transfer occurs from the nitrogen to the negatively charged oxygen, stabilizing the intermediate. 6. **Elimination of Water:** - The intermediate can then lose a water molecule (H2O), leading to the formation of a double bond between the carbon and nitrogen. 7. **Final Product Formation:** - The final product \( X \) will be a hydrazone derivative, which is formed by the condensation of the aldehyde and the hydrazine derivative. 8. **Identify the Product:** - After analyzing the structure, we find that the resulting product matches with one of the options provided in the question. ### Conclusion: Thus, the product \( X \) formed in the reaction is the hydrazone derivative of the unsaturated aldehyde.
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NCERT FINGERTIPS ENGLISH-ALDEHYDES, KETONES AND CARBOXYLIC ACIDS-MCQs( CHEMICAL REACTIONS )
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  2. The best method to purify impure acetone is

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  4. Hydrocarbons are formed when aldehydes and ketones are reacted with am...

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  5. Which of the following statements is incorrect ?

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  6. What is the test to differentiate between pentan - 2- one and pentan -...

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  7. The best oxidising agent for oxidation of CH(3)-CH=CH-CHO" to "CH(3)...

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  8. Which of the following statements is not correct ?

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  9. In the following sequence of reaction, the final product (Z) is CH-...

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  10. Which of the following reagents are not correctly matched with the rea...

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  11. Identify (X), (Y) and (Z) in the given reaction. CH(3)COCH(3) overse...

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  12. Identify (X), (Y) and (Z) reagents in the given sequence of reaction. ...

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  13. Which of the following does not answer iodoform test ?

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  14. A compound 'A' having the molecular formula C(5)H(12)O, on oxidation ...

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  15. To differentiate between pentan -2-one and pentan -3-one a test is ca...

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  16. An organic compound of molecular formula C(3)H(6)O did not give a silv...

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  17. Which is the correct method of synthesising acetamide from acetone?

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  18. Compound (X) with molecular formula C(3)H(8)O is treated with acidifie...

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  19. Which of the following compounds will give a coloured crystalline com...

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  20. Match the column I with column II and mark the appropriate choice .

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