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In the following sequence of reaction, t...

In the following sequence of reaction, the final product (Z) is
`CH-=CH overset(Hg^(2+))underset(H_(2)SO_(4)) to X overset(CH_(3)MgX) underset(H_(2)O) to Y overset([O]) to Z`

A

ethanal

B

propan - 2 - ol

C

propanone

D

propane - 1 - ol

Text Solution

AI Generated Solution

The correct Answer is:
To determine the final product (Z) in the given sequence of reactions, we will analyze each step carefully. ### Step 1: Reaction of Acetylene with Hg²⁺ and H₂SO₄ - **Starting Material**: Acetylene (ethyne), which has the formula C₂H₂. - **Reagents**: Mercury(II) ions (Hg²⁺) and sulfuric acid (H₂SO₄). - **Reaction**: The reaction of acetylene with Hg²⁺ and H₂SO₄ leads to the formation of acetaldehyde (ethanal), which is the first product (X). **Chemical Equation**: \[ \text{C}_2\text{H}_2 + \text{Hg}^{2+} + \text{H}_2\text{SO}_4 \rightarrow \text{CH}_3\text{CHO} \quad (X) \] ### Step 2: Reaction of Acetaldehyde with Methyl Magnesium Halide - **Intermediate Product**: Acetaldehyde (X) is now reacted with methyl magnesium halide (CH₃MgX) in the presence of water (H₂O). - **Reaction**: This reaction is a Grignard reaction, where the Grignard reagent adds to the carbonyl group of acetaldehyde to form a secondary alcohol (Y). **Chemical Equation**: \[ \text{CH}_3\text{CHO} + \text{CH}_3\text{MgX} \xrightarrow{\text{H}_2\text{O}} \text{CH}_3\text{CH(OH)CH}_3 \quad (Y) \] ### Step 3: Oxidation of the Secondary Alcohol - **Intermediate Product**: The secondary alcohol (Y) is then subjected to oxidation. - **Reaction**: Oxidation of the secondary alcohol leads to the formation of a ketone (Z). **Chemical Equation**: \[ \text{CH}_3\text{CH(OH)CH}_3 \xrightarrow{[O]} \text{CH}_3\text{COCH}_3 \quad (Z) \] ### Final Product (Z) - The final product (Z) formed after the oxidation of the secondary alcohol is acetone, also known as propanone. ### Summary of the Reactions: 1. Acetylene reacts with Hg²⁺ and H₂SO₄ to form acetaldehyde (X). 2. Acetaldehyde reacts with methyl magnesium halide to form a secondary alcohol (Y). 3. The secondary alcohol is oxidized to form acetone (Z). ### Final Answer: The final product (Z) is **acetone (propanone)**. ---

To determine the final product (Z) in the given sequence of reactions, we will analyze each step carefully. ### Step 1: Reaction of Acetylene with Hg²⁺ and H₂SO₄ - **Starting Material**: Acetylene (ethyne), which has the formula C₂H₂. - **Reagents**: Mercury(II) ions (Hg²⁺) and sulfuric acid (H₂SO₄). - **Reaction**: The reaction of acetylene with Hg²⁺ and H₂SO₄ leads to the formation of acetaldehyde (ethanal), which is the first product (X). **Chemical Equation**: ...
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NCERT FINGERTIPS ENGLISH-ALDEHYDES, KETONES AND CARBOXYLIC ACIDS-MCQs( CHEMICAL REACTIONS )
  1. The best oxidising agent for oxidation of CH(3)-CH=CH-CHO" to "CH(3)...

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  2. Which of the following statements is not correct ?

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  3. In the following sequence of reaction, the final product (Z) is CH-...

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  4. Which of the following reagents are not correctly matched with the rea...

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  5. Identify (X), (Y) and (Z) in the given reaction. CH(3)COCH(3) overse...

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  6. Identify (X), (Y) and (Z) reagents in the given sequence of reaction. ...

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  7. Which of the following does not answer iodoform test ?

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  8. A compound 'A' having the molecular formula C(5)H(12)O, on oxidation ...

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  9. To differentiate between pentan -2-one and pentan -3-one a test is ca...

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  10. An organic compound of molecular formula C(3)H(6)O did not give a silv...

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  11. Which is the correct method of synthesising acetamide from acetone?

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  12. Compound (X) with molecular formula C(3)H(8)O is treated with acidifie...

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  13. Which of the following compounds will give a coloured crystalline com...

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  14. Match the column I with column II and mark the appropriate choice .

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  15. Few simple chemical tests are given below to differentiate between the...

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  16. Which of the following will not give aldol condensation ?

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  17. The claisen schmidt condensation product of benzaldehyde and acetone i...

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  18. Study the following sequence of reaction and identify the product (Y)....

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  19. Identify (X), (Y) and (Z) in the given reaction. X +Y overset(Z) to ...

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  20. Propanal on treatment with dilute sodium hydroxide gives

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