Home
Class 12
CHEMISTRY
Identify (X), (Y) and (Z) reagents in th...

Identify (X), (Y) and (Z) reagents in the given sequence of reaction.
`CH-=CH overset(X) to CH_(3)CHO overset(Y) to CH_(3)CH(OH)CH_(3) overset(Z) to CH_(3)COCH_(3)`

A

`X=H_(2)SO_(4), Y=H_(2)O//OH^(-), Z=PCl_(5)`, heat

B

`X=HNO_(3), Y=Na_(2)CO_(3),Z=H_(2)SO_(4)`, heat

C

`X=H_(2)SO_(4)//Hg^(2+), Y=PCl_(5)//H_(2)O, Z=K_(2)Cr_(2)O_(7)//OH^(-)`

D

`X=H_(2)SO_(4)//Hg^(2+),Y=CH_(3)MgBr//H_(2)O, Z=K_(2)CrO_(7)//H^(+)`

Text Solution

AI Generated Solution

The correct Answer is:
To solve the problem of identifying the reagents (X), (Y), and (Z) in the given sequence of reactions, we will analyze each step of the transformation from ethyne (CH≡CH) to the final product (CH₃COCH₃). ### Step 1: Identify Reagent (X) The first transformation is from ethyne (CH≡CH) to acetaldehyde (CH₃CHO). To convert an alkyne to an aldehyde, we typically use a reaction known as hydroboration-oxidation. The specific reagent used for this transformation is sulfuric acid (H₂SO₄) in the presence of mercury(II) sulfate (HgSO₄). **Reagent (X):** H₂SO₄ with HgSO₄ (Mercury(II) sulfate) ### Step 2: Identify Reagent (Y) The next step is the conversion of acetaldehyde (CH₃CHO) to 2-propanol (CH₃CH(OH)CH₃). This transformation is achieved through the use of a Grignard reagent. In this case, we can use methylmagnesium bromide (CH₃MgBr) as the Grignard reagent. The Grignard reagent reacts with the carbonyl group of acetaldehyde to form an alcohol. **Reagent (Y):** CH₃MgBr (Methylmagnesium bromide) ### Step 3: Identify Reagent (Z) The final transformation is from 2-propanol (CH₃CH(OH)CH₃) to acetone (CH₃COCH₃). This step involves the oxidation of the alcohol to a ketone. A common oxidizing agent for this transformation is potassium dichromate (K₂Cr₂O₇). **Reagent (Z):** K₂Cr₂O₇ (Potassium dichromate) ### Summary of Reagents - **(X):** H₂SO₄ with HgSO₄ (for hydroboration-oxidation) - **(Y):** CH₃MgBr (Grignard reagent) - **(Z):** K₂Cr₂O₇ (oxidizing agent)
Promotional Banner

Topper's Solved these Questions

  • ALDEHYDES, KETONES AND CARBOXYLIC ACIDS

    NCERT FINGERTIPS ENGLISH|Exercise MCQs( NOMENCLATURE AND STRUCTURE OF CARBOXYL GROUP )|2 Videos
  • ALDEHYDES, KETONES AND CARBOXYLIC ACIDS

    NCERT FINGERTIPS ENGLISH|Exercise MCQs( METHODS OF PREPARATION OF CARBOXYLIC ACIDS )|7 Videos
  • ALDEHYDES, KETONES AND CARBOXYLIC ACIDS

    NCERT FINGERTIPS ENGLISH|Exercise MCQs(PHYSICAL PROPERTIES )|2 Videos
  • ALCOHOLS,PHENOLS AND ETHERS

    NCERT FINGERTIPS ENGLISH|Exercise Assertion And Reason|14 Videos
  • AMINES

    NCERT FINGERTIPS ENGLISH|Exercise ASSERTION & REASON CORNER|14 Videos

Similar Questions

Explore conceptually related problems

Fill in the reagents for the given conversion : CH_(3)COCl overset((X))to CH_(3)CHO overset((Y))to CH_(3)-overset(OH) overset(|)(CH)-CH_(2)CHO overset((Z))to CH_(3)CH=CHCHO

Fill in the reagents for the given conversion : CH_(3)COCl overset((X))to CH_(3)CHO overset((Y))to CH_(3)-overset(OH) overset(|)(CH)-CH_(2)CHO overset((Z))to CH_(3)CH=CHCHO

In the given reaction CH_(3)CH_(2) CH = CHCH_(3) overset(X) to CH_(3)CH_(2)COOH + CH_(3)COOH The X is

Identify (X), (Y) and (Z) in the given reaction. X +Y overset(Z) to underset("3-Hydroxybutanal")(CH_(3)-overset(OH)overset(|)(CH)-CH_(2))-CHO

Identify the reagents A and B respectively in the following reactions CH_3COOH overset(A)(rarr)CH_3COCl overset(B)(rarr)CH_3CHO

CH-=CH overset(O_(3)//NaOH)to X overset(Zn//CH_(3)COOH)to Y . Y is

Identify Z in the sequence of reaaction CH_(3)-CH_(2)-CH=CH_(2) overset(HBr)underset(H_(2)O_(2)//hv)to Z

Ph-CH=CH-CHO overset((i) CH_(3)CH_(2)MgBr)to overset((ii) H_(3)O^(o+))to(X) overset(Cu,Delta)to(Y)

NCERT FINGERTIPS ENGLISH-ALDEHYDES, KETONES AND CARBOXYLIC ACIDS-MCQs( CHEMICAL REACTIONS )
  1. Which of the following reagents are not correctly matched with the rea...

    Text Solution

    |

  2. Identify (X), (Y) and (Z) in the given reaction. CH(3)COCH(3) overse...

    Text Solution

    |

  3. Identify (X), (Y) and (Z) reagents in the given sequence of reaction. ...

    Text Solution

    |

  4. Which of the following does not answer iodoform test ?

    Text Solution

    |

  5. A compound 'A' having the molecular formula C(5)H(12)O, on oxidation ...

    Text Solution

    |

  6. To differentiate between pentan -2-one and pentan -3-one a test is ca...

    Text Solution

    |

  7. An organic compound of molecular formula C(3)H(6)O did not give a silv...

    Text Solution

    |

  8. Which is the correct method of synthesising acetamide from acetone?

    Text Solution

    |

  9. Compound (X) with molecular formula C(3)H(8)O is treated with acidifie...

    Text Solution

    |

  10. Which of the following compounds will give a coloured crystalline com...

    Text Solution

    |

  11. Match the column I with column II and mark the appropriate choice .

    Text Solution

    |

  12. Few simple chemical tests are given below to differentiate between the...

    Text Solution

    |

  13. Which of the following will not give aldol condensation ?

    Text Solution

    |

  14. The claisen schmidt condensation product of benzaldehyde and acetone i...

    Text Solution

    |

  15. Study the following sequence of reaction and identify the product (Y)....

    Text Solution

    |

  16. Identify (X), (Y) and (Z) in the given reaction. X +Y overset(Z) to ...

    Text Solution

    |

  17. Propanal on treatment with dilute sodium hydroxide gives

    Text Solution

    |

  18. Aldehydes that do not undergo aldol condensation are (1) propanal (...

    Text Solution

    |

  19. The order of reactivity of CH(3)CHO, CH(3)COC(2)H(5) and CH(3)COCH(3) ...

    Text Solution

    |

  20. The final product (Y) in the following sequence of chemical reaction i...

    Text Solution

    |