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Study the following sequence of reaction...

Study the following sequence of reaction and identify the product (Y).
`CH_(3)CHO +HCHO overset("dil."NaOH)underset("heat") to X overset(HCN) underset(H_(3)O^(+)) to Y`

A

`CH_(2)=CH-underset(OH)underset(|)(CH)-COOH`

B

`CH_(3)-overset(CN)overset(|)underset(OH)underset(|)C-COOH`

C

`CH_(3)CH_(2)-underset(OH) underset(|)CH-COOH`

D

`CH_(2)=CH-underset(CN)underset(|)(CH)-COOH`

Text Solution

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The correct Answer is:
To solve the problem, we need to analyze the given reactions step by step. ### Step 1: Identify the first reaction The first reaction involves acetaldehyde (CH₃CHO) reacting with formaldehyde (HCHO) in the presence of dilute NaOH and heat. This reaction is known as aldol condensation. 1. **Write the reactants:** - Acetaldehyde (CH₃CHO) - Formaldehyde (HCHO) 2. **Identify the aldol condensation:** - Aldol condensation requires at least one of the reactants to have an alpha-hydrogen. Acetaldehyde has an alpha-hydrogen (the hydrogen on the carbon adjacent to the carbonyl group). 3. **Mechanism of aldol condensation:** - The hydroxide ion (OH⁻) from NaOH will deprotonate the alpha-hydrogen of acetaldehyde, forming an enolate ion. - The enolate ion will then attack the carbonyl carbon of formaldehyde, leading to the formation of a β-hydroxy aldehyde (the aldol product). 4. **Formulate the product (X):** - The product (X) after aldol condensation will be 3-hydroxybutanal (CH₃CH(OH)CH₂CHO). ### Step 2: Identify the second reaction The second reaction involves the product (X) reacting with HCN in the presence of H₃O⁺. 1. **Write the reactant:** - The product from the first reaction: 3-hydroxybutanal (CH₃CH(OH)CH₂CHO). 2. **Mechanism of cyanohydrin formation:** - The carbonyl group (CHO) of 3-hydroxybutanal can react with HCN to form a cyanohydrin. - The hydroxyl group (OH) will remain, and the CN group will add to the carbonyl carbon. 3. **Formulate the product (Y):** - The product (Y) after this reaction will be 3-hydroxybutyronitrile (CH₃CH(OH)CH₂CN). ### Final Product The final product (Y) is 3-hydroxybutyronitrile. ### Conclusion Thus, the product (Y) is **3-hydroxybutyronitrile**.

To solve the problem, we need to analyze the given reactions step by step. ### Step 1: Identify the first reaction The first reaction involves acetaldehyde (CH₃CHO) reacting with formaldehyde (HCHO) in the presence of dilute NaOH and heat. This reaction is known as aldol condensation. 1. **Write the reactants:** - Acetaldehyde (CH₃CHO) - Formaldehyde (HCHO) ...
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NCERT FINGERTIPS ENGLISH-ALDEHYDES, KETONES AND CARBOXYLIC ACIDS-MCQs( CHEMICAL REACTIONS )
  1. Which of the following will not give aldol condensation ?

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  2. The claisen schmidt condensation product of benzaldehyde and acetone i...

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  3. Study the following sequence of reaction and identify the product (Y)....

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  4. Identify (X), (Y) and (Z) in the given reaction. X +Y overset(Z) to ...

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  5. Propanal on treatment with dilute sodium hydroxide gives

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  6. Aldehydes that do not undergo aldol condensation are (1) propanal (...

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  7. The order of reactivity of CH(3)CHO, CH(3)COC(2)H(5) and CH(3)COCH(3) ...

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  8. The final product (Y) in the following sequence of chemical reaction i...

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  9. Which of the following is a correct statement ?

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  10. Which of the following is the most reactive isomer ?

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  11. When propanal reacts with 2- methylpropanal in presence of NaOH, four ...

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  12. Fill in the reagents for the given conversion : CH(3)COCl overset((...

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  13. Which compound is obtained when acetaldehyde is treated with dilute s...

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  14. Which of the following compounds will undergo self aldol condensation ...

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  15. Which of the following compounds will undergo Cannizzaro reaction ?

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  16. Which of the following does not undergo Cannizzaro reaction?

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  17. Fill in the blanks by suitable choices. The carbon atom in carbonyl ...

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  18. Which of the following aldehydes will show Cannizzaro reaction ?

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  19. overset(" CHO")underset(" CHO")("|")overset(NaOH)toX The product...

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  20. An organic compound (X) with molecular formula C(9)H(10)O gives positi...

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