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The order of reactivity of CH(3)CHO, CH(...

The order of reactivity of `CH_(3)CHO, CH_(3)COC_(2)H_(5) and CH_(3)COCH_(3) ` is

A

`CH_(3)CHO gt CH_(3)COCH_(3) gt CH_(3)COC_(2)H_(5)`

B

`C_(2)H_(5)COCH_(3) gt CH_(3)COCH_(3) gt CH_(3)CHO`

C

`CH_(3)COCH_(3) gt CH_(3)CHO gt C_(2)H_(2)COCH_(3)`

D

`CH_(3)COCH_(3) gt C_(2)H_(5)COCH_(3) gt CH_(3)CHO`

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The correct Answer is:
To determine the order of reactivity of the compounds \( CH_3CHO \) (acetaldehyde), \( CH_3COC_2H_5 \) (ethyl methyl ketone), and \( CH_3COCH_3 \) (acetone), we need to analyze their stability and how that relates to their reactivity. ### Step 1: Identify the Compounds - **Compound 1**: \( CH_3CHO \) (Acetaldehyde) - **Compound 2**: \( CH_3COC_2H_5 \) (Ethyl Methyl Ketone) - **Compound 3**: \( CH_3COCH_3 \) (Acetone) ### Step 2: Understand Reactivity and Stability Reactivity is inversely proportional to stability. This means that the less stable a compound is, the more reactive it will be. ### Step 3: Analyze the Stability of Each Compound 1. **Acetaldehyde (\( CH_3CHO \))**: - It has a carbonyl group (C=O) and is an aldehyde. Aldehydes are generally more reactive than ketones due to less steric hindrance and the presence of a hydrogen atom attached to the carbonyl carbon. 2. **Ethyl Methyl Ketone (\( CH_3COC_2H_5 \))**: - This is a ketone with two alkyl groups. The presence of the ethyl group provides a +I (inductive) effect, which stabilizes the positive charge that can develop during reactions. 3. **Acetone (\( CH_3COCH_3 \))**: - Acetone is also a ketone, but it has two methyl groups. The +I effect from two methyl groups is significant, making acetone more stable than ethyl methyl ketone. ### Step 4: Compare Stability - **Stability Order**: - \( CH_3COCH_3 \) (most stable, due to two +I effects from methyl groups) - \( CH_3COC_2H_5 \) (less stable than acetone, due to one +I effect) - \( CH_3CHO \) (least stable, as it is an aldehyde) ### Step 5: Determine the Reactivity Order Since reactivity is inversely proportional to stability: - **Reactivity Order**: - \( CH_3CHO > CH_3COC_2H_5 > CH_3COCH_3 \) ### Final Answer The order of reactivity is: \[ CH_3CHO > CH_3COC_2H_5 > CH_3COCH_3 \]

To determine the order of reactivity of the compounds \( CH_3CHO \) (acetaldehyde), \( CH_3COC_2H_5 \) (ethyl methyl ketone), and \( CH_3COCH_3 \) (acetone), we need to analyze their stability and how that relates to their reactivity. ### Step 1: Identify the Compounds - **Compound 1**: \( CH_3CHO \) (Acetaldehyde) - **Compound 2**: \( CH_3COC_2H_5 \) (Ethyl Methyl Ketone) - **Compound 3**: \( CH_3COCH_3 \) (Acetone) ### Step 2: Understand Reactivity and Stability ...
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NCERT FINGERTIPS ENGLISH-ALDEHYDES, KETONES AND CARBOXYLIC ACIDS-MCQs( CHEMICAL REACTIONS )
  1. The claisen schmidt condensation product of benzaldehyde and acetone i...

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  2. Study the following sequence of reaction and identify the product (Y)....

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  3. Identify (X), (Y) and (Z) in the given reaction. X +Y overset(Z) to ...

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  4. Propanal on treatment with dilute sodium hydroxide gives

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  5. Aldehydes that do not undergo aldol condensation are (1) propanal (...

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  6. The order of reactivity of CH(3)CHO, CH(3)COC(2)H(5) and CH(3)COCH(3) ...

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  7. The final product (Y) in the following sequence of chemical reaction i...

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  8. Which of the following is a correct statement ?

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  9. Which of the following is the most reactive isomer ?

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  10. When propanal reacts with 2- methylpropanal in presence of NaOH, four ...

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  11. Fill in the reagents for the given conversion : CH(3)COCl overset((...

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  12. Which compound is obtained when acetaldehyde is treated with dilute s...

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  13. Which of the following compounds will undergo self aldol condensation ...

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  14. Which of the following compounds will undergo Cannizzaro reaction ?

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  15. Which of the following does not undergo Cannizzaro reaction?

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  16. Fill in the blanks by suitable choices. The carbon atom in carbonyl ...

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  17. Which of the following aldehydes will show Cannizzaro reaction ?

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  18. overset(" CHO")underset(" CHO")("|")overset(NaOH)toX The product...

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  19. An organic compound (X) with molecular formula C(9)H(10)O gives positi...

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  20. What are correct steps to convert acetaldehyde to acetone?

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