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Fill in the reagents for the given conve...

Fill in the reagents for the given conversion :
`CH_(3)COCl overset((X))to CH_(3)CHO overset((Y))to CH_(3)-overset(OH) overset(|)(CH)-CH_(2)CHO overset((Z))to CH_(3)CH=CHCHO`

A

`{:(X,Y,Z),(H_2//Pd//BaSO_(4),"dil. "NaOH, "heat") :}`

B

`{:(X,Y,Z),(NaOH,"Hydrolysis","heat"):}`

C

`{:(X,Y,Z),(I_(2)//NaOH,LiAlH_(4), H_(3)O^(+)):}`

D

`{:(X,Y,Z),(CrO_(3),"Warm",CO_(2)):}`

Text Solution

AI Generated Solution

The correct Answer is:
To fill in the reagents for the given conversion, we will analyze each step of the reaction sequence. ### Step 1: Conversion of Acetyl Chloride to Acetaldehyde **Reaction:** \[ \text{CH}_3\text{COCl} \xrightarrow{(X)} \text{CH}_3\text{CHO} \] **Reagent (X):** The conversion of acetyl chloride (CH₃COCl) to acetaldehyde (CH₃CHO) can be achieved through the Rosenmund reduction. The reagent used for this reaction is: \[ \text{H}_2 \text{(g)}, \text{Pd/BaSO}_4 \] This is a catalytic hydrogenation process where palladium on barium sulfate acts as a catalyst in the presence of hydrogen gas. ### Step 2: Conversion of Acetaldehyde to Beta-Hydroxy Carbonyl Compound **Reaction:** \[ \text{CH}_3\text{CHO} \xrightarrow{(Y)} \text{CH}_3\text{CH(OH)CH}_2\text{CHO} \] **Reagent (Y):** The conversion of acetaldehyde to a beta-hydroxy carbonyl compound is done through an aldol condensation reaction. The reagent used for this reaction is: \[ \text{Dilute NaOH} \] This base facilitates the deprotonation of the alpha hydrogen, leading to the formation of an enolate ion, which then reacts with another molecule of acetaldehyde. ### Step 3: Conversion of Beta-Hydroxy Carbonyl Compound to Alpha, Beta-Unsaturated Carbonyl Compound **Reaction:** \[ \text{CH}_3\text{CH(OH)CH}_2\text{CHO} \xrightarrow{(Z)} \text{CH}_3\text{CH=CHCHO} \] **Reagent (Z):** The conversion of the beta-hydroxy carbonyl compound to an alpha, beta-unsaturated carbonyl compound involves dehydration (removal of water). The reagent typically used for this step is: \[ \text{Heat} \] Heating the beta-hydroxy carbonyl compound promotes the elimination of water, resulting in the formation of the double bond. ### Summary of Reagents: - **(X)**: H₂ (g), Pd/BaSO₄ - **(Y)**: Dilute NaOH - **(Z)**: Heat ---
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The IUPAC name of CH_(2)overset(OH)overset(|)(CH)CH_(2)overset(CH_(3))overset(|)(CH)CHO is

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The IUPAC name of CH_(3)-overset(O)overset(||)(C)-CH_(2)-overset(OH)overset(|)(CH)-CHO is

The IUPAC name of CH_(3)-overset(O)overset(||)(C)-CH_(2)-overset(OH)overset(|)(CH)-CHO is

Identify (X), (Y) and (Z) reagents in the given sequence of reaction. CH-=CH overset(X) to CH_(3)CHO overset(Y) to CH_(3)CH(OH)CH_(3) overset(Z) to CH_(3)COCH_(3)

The IUPAC name of the following compound is: H_(3)C-overset(CH_(3))overset(|)CH-overset(OH)overset(|)CH-CH_(2)-COOH

The IUPAC name of the following compound is H_(3)C-overset(CH_(3))overset("| ")"CH"-overset(OH)overset("| ")"CH"-CH_(2)-COOH

Write the reagents to carry out following conversions: CH_(3)overset(O)overset(||)C Cloverset(II......)rarrCH_(3)overset(O)overset(||)C Hoverset(I......)rarrCH_(3)CH_(2)OH

NCERT FINGERTIPS ENGLISH-ALDEHYDES, KETONES AND CARBOXYLIC ACIDS-MCQs( CHEMICAL REACTIONS )
  1. The claisen schmidt condensation product of benzaldehyde and acetone i...

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  2. Study the following sequence of reaction and identify the product (Y)....

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  3. Identify (X), (Y) and (Z) in the given reaction. X +Y overset(Z) to ...

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  4. Propanal on treatment with dilute sodium hydroxide gives

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  5. Aldehydes that do not undergo aldol condensation are (1) propanal (...

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  6. The order of reactivity of CH(3)CHO, CH(3)COC(2)H(5) and CH(3)COCH(3) ...

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  7. The final product (Y) in the following sequence of chemical reaction i...

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  8. Which of the following is a correct statement ?

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  9. Which of the following is the most reactive isomer ?

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  10. When propanal reacts with 2- methylpropanal in presence of NaOH, four ...

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  11. Fill in the reagents for the given conversion : CH(3)COCl overset((...

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  12. Which compound is obtained when acetaldehyde is treated with dilute s...

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  13. Which of the following compounds will undergo self aldol condensation ...

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  14. Which of the following compounds will undergo Cannizzaro reaction ?

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  15. Which of the following does not undergo Cannizzaro reaction?

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  16. Fill in the blanks by suitable choices. The carbon atom in carbonyl ...

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  17. Which of the following aldehydes will show Cannizzaro reaction ?

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  18. overset(" CHO")underset(" CHO")("|")overset(NaOH)toX The product...

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  19. An organic compound (X) with molecular formula C(9)H(10)O gives positi...

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  20. What are correct steps to convert acetaldehyde to acetone?

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