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The end product (Z) in the given sequenc...

The end product (Z) in the given sequence of reaction is
`CH_(3)CH=CHCHO overset(NaBH_(4))toXoverset(HCl)underset(ZnCl_(2))toY overset((i)KCN)underset((ii)H+)toZ`

A

`CH_(3)CH=CHCH_(2)COOH`

B

`CH_(3)CH_(2)CH_(2)COOH`

C

`CH_(3)CH=CHCOOH`

D

`CH_(3)CH(Cl)CH_(2)COOH`

Text Solution

AI Generated Solution

The correct Answer is:
To solve the question step by step, we will analyze each reaction in the sequence provided and identify the end product (Z). ### Step 1: Identify the starting compound The starting compound is given as CH₃CH=CHCHO, which is an alpha, beta-unsaturated carbonyl compound. ### Step 2: Reduction with Sodium Borohydride (NaBH₄) When CH₃CH=CHCHO is treated with sodium borohydride (NaBH₄), it acts as a mild reducing agent. It will reduce the carbonyl group (the aldehyde) to an alcohol while leaving the double bond intact. The reaction can be represented as follows: \[ \text{CH}_3\text{CH}=\text{CHCHO} + \text{NaBH}_4 \rightarrow \text{CH}_3\text{CH}=\text{CH-CH}_2\text{OH} \] This product is denoted as X: \[ X = \text{CH}_3\text{CH}=\text{CH-CH}_2\text{OH} \] ### Step 3: Reaction with HCl and ZnCl₂ (Lucas Reagent) Next, the compound X reacts with hydrochloric acid (HCl) and zinc chloride (ZnCl₂), which is known as Lucas reagent. The alcohol group (–OH) in X will be protonated to form a better leaving group (water), leading to the formation of a carbocation. The reaction can be represented as: 1. Protonation of the alcohol: \[ \text{CH}_3\text{CH}=\text{CH-CH}_2\text{OH} + \text{HCl} \rightarrow \text{CH}_3\text{CH}=\text{CH-CH}_2\text{OH}_2^+ \] 2. Loss of water to form a carbocation: \[ \text{CH}_3\text{CH}=\text{CH-CH}_2\text{OH}_2^+ \rightarrow \text{CH}_3\text{CH}=\text{CH-CH}_2^+ + \text{H}_2\text{O} \] 3. Nucleophilic attack by chloride ion: \[ \text{CH}_3\text{CH}=\text{CH-CH}_2^+ + \text{Cl}^- \rightarrow \text{CH}_3\text{CH}=\text{CH-CH}_2\text{Cl} \] This product is denoted as Y: \[ Y = \text{CH}_3\text{CH}=\text{CH-CH}_2\text{Cl} \] ### Step 4: Reaction with KCN The compound Y then reacts with potassium cyanide (KCN). In this step, the cyanide ion (CN⁻) acts as a nucleophile and attacks the electrophilic carbon atom bonded to the chlorine atom. The reaction can be represented as: \[ \text{CH}_3\text{CH}=\text{CH-CH}_2\text{Cl} + \text{KCN} \rightarrow \text{CH}_3\text{CH}=\text{CH-CH}_2\text{CN} + \text{Cl}^- \] This product is denoted as Z: \[ Z = \text{CH}_3\text{CH}=\text{CH-CH}_2\text{CN} \] ### Step 5: Hydrolysis of the Nitrile The final step involves the hydrolysis of the nitrile (–CN) group to convert it into a carboxylic acid (–COOH). This can be done by treating the compound Z with an acid (H⁺). The hydrolysis reaction can be represented as: \[ \text{CH}_3\text{CH}=\text{CH-CH}_2\text{CN} + \text{H}_2\text{O} \rightarrow \text{CH}_3\text{CH}=\text{CH-CH}_2\text{COOH} \] Thus, the final product Z is: \[ Z = \text{CH}_3\text{CH}=\text{CH-CH}_2\text{COOH} \] ### Conclusion The end product Z in the given sequence of reactions is: \[ \text{Z} = \text{CH}_3\text{CH}=\text{CH-CH}_2\text{COOH} \]

To solve the question step by step, we will analyze each reaction in the sequence provided and identify the end product (Z). ### Step 1: Identify the starting compound The starting compound is given as CH₃CH=CHCHO, which is an alpha, beta-unsaturated carbonyl compound. ### Step 2: Reduction with Sodium Borohydride (NaBH₄) When CH₃CH=CHCHO is treated with sodium borohydride (NaBH₄), it acts as a mild reducing agent. It will reduce the carbonyl group (the aldehyde) to an alcohol while leaving the double bond intact. ...
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