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Reaction : 2Fe^(3+)+Zn to Zn^(2+)+2Fe^(2...

Reaction : `2Fe^(3+)+Zn to Zn^(2+)+2Fe^(2+)`, is carried out in electrochemical cell, then on increasing concentration of `Fe^(2+)` what will be observed ?

A

Cell potential increases

B

Cell potential decreases

C

Increase in current.

D

pH of solution decreases

Text Solution

Verified by Experts

The correct Answer is:
B

`E_(cell)=E_(cell)^(o)-(0.0592)/(n)"log"(["The concentration of product"])/(["The concentration of reactant"])`
From above equation, on increasing `Fe^(2+)` concentration, `E_(cell)` value decreases by subtracting from `E_(cell)^(@)` value.
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