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In presence of HCl, H2S results the prec...

In presence of HCl, `H_2S` results the precipitatiion of Group-2 elements but not Group -4 elements during qualitative analysis. If is due to

A

Lower concentration of `H^(+)`

B

Lower concentration of `S^(2-)`

C

Higher concentration of `H^(+)`

D

Higher concentration of `S^(2-)`

Text Solution

Verified by Experts

The correct Answer is:
B

Dissociation of `H_2S` is suppressed in presence of HCl due to common ion effect. This decreases the `S^(-2)` ion concentration and hence, only group II radicals having low solubility product are precipitated.
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