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0.30g of an organic compound contaiining...

0.30g of an organic compound contaiining C, H and Oxygen an combustion yields 0.44g `CO_2` and 0.18g `H_2O`. If one mol of compound weight 60, then molecular formula of the compound is

A

`C_2H_4O_2`

B

`C_4H_6O`

C

`C_3H_8O`

D

`CH_2O`

Text Solution

Verified by Experts

The correct Answer is:
A

Percentage of `C = 12/44 xx 0.44/0.30 xx 100 = 40%`
Percentage of `H= 12/18 xx 0.18/0.30 xx 100 = 6.6%`
Percentage of `O = 100-(40 + 6.6) = 53.4%`

Hence empirical formula `= CH_2O`
`n = ("Molecular mass")/("Emperical formula mass") =60/30 = 2`
`rArr ` Molecular formula of the compound ` = (CH_2O)_2 = C_2H_4O_2`
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