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which among the following statement is incorrect regarding the product formed when two molecules of HBr add to ethyne?

A

IUPAC name is 1,1-dibromomethene

B

it is a geminal dihalide

C

It is a position isomer of 1,2-dibromomethene

D

It has a planer structure

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The correct Answer is:
To determine which statement is incorrect regarding the product formed when two molecules of HBr add to ethyne, we can follow these steps: ### Step 1: Understand the Reaction When ethyne (C₂H₂) reacts with HBr, it undergoes an addition reaction. The first molecule of HBr adds across the triple bond, resulting in a vinyl bromide (bromoethene). The second molecule of HBr adds to the double bond, leading to the formation of a dibromide. **Hint:** Consider the mechanism of electrophilic addition and how Markovnikov's rule applies. ### Step 2: Identify the Product The addition of two HBr molecules to ethyne results in the formation of 1,1-dibromoethane. This is because both bromine atoms will attach to the same carbon atom due to Markovnikov's rule, which states that the more substituted carbon will receive the halogen. **Hint:** Recall the concept of Markovnikov's rule and how it influences the addition of reagents to alkenes and alkynes. ### Step 3: Determine the IUPAC Name The product formed, 1,1-dibromoethane, has two bromine atoms attached to the same carbon (the first carbon). Thus, the IUPAC name is indeed 1,1-dibromoethane. **Hint:** Remember the naming conventions for organic compounds, especially for dihalides. ### Step 4: Analyze the Statements 1. **Statement 1:** "1,1-dibromo-methane" - This is incorrect because the product is 1,1-dibromoethane, not methane. 2. **Statement 2:** "It is a geminal dihalide" - This is correct as both bromine atoms are on the same carbon. 3. **Statement 3:** "It has a planar structure" - This is incorrect because the carbon atoms in 1,1-dibromoethane are sp³ hybridized, leading to a tetrahedral structure, not planar. 4. **Statement 4:** "It is a position isomer of 1,2-dibromo-ethane" - This is correct as they differ in the position of bromine atoms. **Hint:** Carefully evaluate each statement based on the structure and properties of the product. ### Conclusion The incorrect statements regarding the product formed when two molecules of HBr add to ethyne are: - Statement 1: "1,1-dibromo-methane" (incorrect name) - Statement 3: "It has a planar structure" (incorrect structure) ### Final Answer The incorrect statements are Statement 1 and Statement 3.
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