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Structures and IUPAC names of some hydro...

Structures and IUPAC names of some hydrocarbons are given below. Explain why the names given in the parentheses are incorrect.
(a) `underset("2, 5,6-Trimethyloctane (and not 3,4,7-Trimethyloctane)")(CH_(3) - underset(underset(CH_(3))(|))(CH)- CH_(2) - CH_(2) - underset(underset(CH_(3))(|))(CH)-underset(underset(CH_(3))(|))(CH)-CH_(2) - CH_(3))`
(b) `underset("3-Ethyl-5-methylheptane (and not 5-Ethyl-3-methylheptane)")(CH_(3) - CH_(2) - underset(underset(CH_(2)CH_(3))(|))(CH)- CH_(2) - underset(underset(CH_(3))(|))(CH)- CH_(2) - CH_(3))`

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(a) Lowest locant number, 2, 5, 6 is lower than 3, 5, 7
(b) Substituents are in equivalent position, lower number is given to the one that comes first in the name according to alphabetical order
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KUMAR PRAKASHAN-ORGANIC CHEMISTRY SOME BASIC PRINCIPLES AND TECHNIQUES-Section A -Problem
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  2. Write dash formula and complete structural formula of 2, 4-dimethylpen...

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  3. Structures and IUPAC names of some hydrocarbons are given below. Expla...

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  4. CH(3) - CH(2) - CH - overset(overset(CH(CH(3))(2))(|))(CH) - underset(...

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  5. In above problem -26, why the IUPAC name 4-isopropyl-5-secondary butyl...

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  6. H(3)C- underset(underset(CH(3))(|))(CH) - CH(2) - underset(underset(CH...

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  7. Give the correct order of substitute group in the following (a) H(3)...

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  8. Write IUPAC name of following: (i) (CH(3))(4)C (b) [(CH(3))(2) CH] C...

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  9. Write IUPAC name and write condensed structure, dash structure line fo...

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  10. Write the IUPAC names of the compounds i-iv from their given structure...

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  11. Derivce the sturcture of (i) 2-Chlorohexane (ii) Pent -4-en-2-ol (ii...

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  12. Which of the following represents the correct IUPAC name for the compo...

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  13. Give IUPAC name of following (i) CH(3)COOCH(3) (ii) CH(3)COOCH(2)CH(...

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  14. Derive IUPAC name of following:

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  15. Write the structural formula of: (a) o-ethylanisole (b) p-nitroanili...

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  16. Give the IUPAC names of the following compounds: Cl(2)CHCH(2)OH

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  17. Draw formulas for the first five members of each homologous series beg...

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  18. Identify the functional groups in the following compounds:

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  19. Give structure and name of one double bond containing cyclic compound

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  20. Which of the main functional group in the following ? (a) CH(2)OH -C...

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