Home
Class 12
CHEMISTRY
i) Explain Hoffmann bromamide degradatio...

i) Explain Hoffmann bromamide degradation for the preparation of aniline.
ii) Give the IUPAC name of `CH_(3)-NH-CH_(2)-CH_(3)`. 

Text Solution

Verified by Experts

a) i) When amides are heated with bromine and NaOH/KOH (alcoholic/aqueous) Hoffmann.s bromamide degradation takes place leading to the formation of amines containing one carbon atom less than the respective amide.
`underset("Amide")(R-overset(O)overset(||)C-NH_(2))+Br_(2)+4NaOH rarr underset("Amine")(R-NH_(2))+Na_(2)CO_(3)+2NaBr+2H_(2)O`
ii) The IUPAC name is N-methylethánaminie.
Promotional Banner

Topper's Solved these Questions

  • II PUC CHEMISTRY (ANNUAL EXAM QUESTION PAPER MARCH - 2014)

    SUNSTAR PUBLICATION|Exercise PART - C|8 Videos
  • II PUC CHEMISTRY ( ANNUAL EXAM QUESTION PAPER MARCH - 2020)

    SUNSTAR PUBLICATION|Exercise PART-D|32 Videos
  • II PUC CHEMISTRY (ANNUAL EXAM QUESTION PAPER MARCH - 2015)

    SUNSTAR PUBLICATION|Exercise PART - D|26 Videos

Similar Questions

Explore conceptually related problems

Explain Hoffman bromamide degradation for the preparation of aniline.

Explain Hoffmann bromamide degradation for the preparation of methanamine.

Give the IUPAC name of CH_(3)CHO

Give the IUPAC name of CH_(2)=CH-CHO .

Give IUPAC name of CH_(3)CHO .

Write the IUPAC name of (CH_(3))_(2)N-CH_(2)-CH_(3) .

Give the IUPAC name of CH_3-CH_2-CH=CH-COOH

Explain Hoffmann's bromamide degradation reaction for the preparation of methanamine.

Explain Hoffmann's bromamide degradation reaction for the preparation of methanamine.

Write the IUPAC name of CH_(3)COCH_(2) CH_(2)CH_(3) .

SUNSTAR PUBLICATION-II PUC CHEMISTRY (ANNUAL EXAM QUESTION PAPER MARCH - 2014)-PART - D
  1. On dissolving 2.34g of non-electrolyte solute in 40g of benzene, the b...

    Text Solution

    |

  2. State Henry's law. Write its mathematical form.

    Text Solution

    |

  3. Draw a neat labeled diagram of Standard Hydrogen Electrode (SHE). Writ...

    Text Solution

    |

  4. b) Calculate Delta(r)G^(@) for the following reaction: Fe((aq))^(+2)...

    Text Solution

    |

  5. a) The rate of a particular reaction doubles when the temperature chan...

    Text Solution

    |

  6. b) Show that the half - life period of a first order reaction is indep...

    Text Solution

    |

  7. Write any two differences between physisorption and chemisorption.

    Text Solution

    |

  8. i) Mention the role of alum in the purification of drinking water. i...

    Text Solution

    |

  9. a) i) write the equations for the steps in SN1 mechanism of the conver...

    Text Solution

    |

  10. b) Complete the following equation: i) C(2)H(5)OH+SOCl(2)rarr ii)

    Text Solution

    |

  11. i) Explain the preparation of phenol from cumene. ii) Complete the r...

    Text Solution

    |

  12. Explain Williamson's ether synthesis.

    Text Solution

    |

  13. i) How do you convert benzoic acid to benzamide? Write the reaction. ...

    Text Solution

    |

  14. What happens when the carbonly compounds are treated with hydrazine? W...

    Text Solution

    |

  15. i) Explain Hoffmann bromamide degradation for the preparation of anili...

    Text Solution

    |

  16. b) What is Hinsberg's reagent? Between CH(3)NH(2) and C(6)H(5)NH(2) wh...

    Text Solution

    |

  17. i) Name the water insoluble component of starch. ii) Mention one wat...

    Text Solution

    |

  18. Write the structure of Maltose.

    Text Solution

    |

  19. i) Explain the preparation of Buna-N. ii) Give an example for thermo...

    Text Solution

    |

  20. Name the monomers used in the preparation of polythene and natural rub...

    Text Solution

    |